李根2015毕业论文.doc

目 录 摘要 II 关键词 II Abstract III Key words III 1.文献综述 1 1.1 PP的简介 1 1.2 PP的改性研究进展 1 1.3 PA6的简介及应用 2 1.4 PP/PA6共混物的研究进展 3 1.5 POE-g-GMA的应用 4 1.6本课题研究的主要目的以及意义 6 2实验 6 2.1主要原料 6 2.2主要仪器和设备 7 2.3试样制备 7 2.4测试与表征 8 3.结果与讨论 10 3.1 POE-g-GMA及纯POE的红外分析： 10 3.2接枝率的测定分析： 11 3.3 PP/PA6共混物力学性能分析： 12 3.4 POE-g-GMA接枝PP/PA6共混物力学性能分析： 14 3.5 PP/PA6共混物及PP/PA6/POE-g-GMA共混物力学性能比较 16 4 结论 17 参考文献 18 致谢 20 POE-g-GMA的制备及其增容PP/PA6共混物的性能研究 摘要：采用熔融法制备乙烯-辛烯共聚物接枝甲基丙烯酸缩水甘油酯(POE-g-GMA)。利用红外光谱法和化学滴定法对接枝物进行表征及接枝率的测定。并将POE-g-GMA作为相容剂对PP/PA6的力学性能的影响进行研究。研究结果表明：在PP/PA6共混体系中加入相容剂POE-g-GMA不仅能够改善PP/PA6共混物的相容性，而且能够使PP/PA6共混物在保持较高拉伸强度和弹性模量的同时，大幅度地提高共混物的缺口冲击度和断裂伸长率，与纯PP相比提高幅度显著增大。 关键词：乙烯辛烯共聚物；甲基丙烯酸缩水甘油酯；熔融接枝；化学滴定法；力学性能 Preparation of POE-g-GMA and Its Application Study on Toughening PP/PA6composite membranes Abstract: The copolymer of GMA grafting POE was prepared by melting process in a co-rotating twin-screw extruder.The character and graft yield of the copolymer were studied by FTIR and titration. polyanide6 blends were studied. And the effect of mechanical properties of POE-g-GMA as a compatibility agent on PP/PA6 blends was studied. Research results showed that the addition of appropriate amount of PA6 in the blends of PP/PA6 can improve the tensile strength of PP, when the addition of the compatibility POE-g-GMA in PP/PA6 blend system, not only can improve the compatibility of PP/PA6 blends, and can make the PP/PA6 blends while keeping high tensile strength and modulus of elasticity at the same time, greatly improve the notched impact and the elongation at break of the blends, compared with pure PP improve significantly increased. Key words: ethylene/octane copolymer；glycidyl methacrylate；melt grafting；chemical titration；structure proper； 1.文献综述 1.1 PP聚丙烯英文名称：Polypropylene，简称：PP，俗称：百折胶。聚丙烯是聚α-烯烃的代表，由丙烯聚合而制得的一种热塑性树脂，其单体是丙烯CH2=CH－CH3。在汽车工业、家用电器、电子、包装及建材、家具等方面具有广泛的应用，聚丙烯是一种性能优异的聚烯烃材料，自1957年由意大利的Mont公司实现工业化以来，它是五大通用热塑性树脂中发展历史最短、增长最快的品种。聚丙烯之所以能获得如此迅速的发展，有以下几个方面的原因：（1）综合性能优良，性能范围宽；（2）无毒害、易回收，具有环保优势；（3