磁场作用下铁在盐酸与氯化钠溶液中自腐蚀状态的变化_吕战鹏.pdf

23 5 Vol. 23 No.5 2002 5 C RR SI N PR TECT I N May 2002 试验研究 , , ( , 200437) : , ; , : ; ; ; ; ; : TG172.6 : A : 1005-748X(2002)05-0185-05 MAGNETIC FIELD INDUCED VARIATI N F PEN CIRCUIT STATE F IR N IN CHL RIDE S LUTI NS LU Zhan-peng, HUANGDe-lun, YANG Wu ( Shanghai Research Institute of Materials, Shanghai 200437, China) Abstract: Effects of magneticfield on the open circuit state of iron in acidic or neutralchloride solutions were stud- ied by electrode potential measurements and potentiostatic polarization with magnetic field perturbation. pen circuit po- tential ( E or E ) moved toward the positive direction after imposing magneticfield, and E moved toward the nega- corr c corr tive direction after withdrawing magnetic field. When iron was potentiostatically polarized at the open circuit potential without magneticfield, a cathodic current wasobserved after imposing magneticfield. An anodic current was detected af- ter withdrawing magneticfield for iron potentiostatically polarized at the open circuit potential with magnetic field. Mag- netic fieldinduced cathodic current was larger in acidic solution than in neutral solution, supporting the evidence that mag- neticfield affected the open circuit state mainly by accelerating the cathodic hydrogen evolution reaction. Key words: Magnetic field; Iron; Chloride solution; pen circuit state; Potentiostatic polarization; Hydrogen evolution reaction HCl NaCl , Srivastava ( 0. 07T)