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23 5 Vol. 23 No.5
2002 5 C RR SI N PR TECT I N May 2002
试验研究
, ,
( , 200437)
:
,
;
,
: ; ; ; ; ;
: TG172.6 : A : 1005-748X(2002)05-0185-05
MAGNETIC FIELD INDUCED VARIATI N F PEN CIRCUIT STATE F
IR N IN CHL RIDE S LUTI NS
LU Zhan-peng, HUANGDe-lun, YANG Wu
( Shanghai Research Institute of Materials, Shanghai 200437, China)
Abstract: Effects of magneticfield on the open circuit state of iron in acidic or neutralchloride solutions were stud-
ied by electrode potential measurements and potentiostatic polarization with magnetic field perturbation. pen circuit po-
tential ( E or E ) moved toward the positive direction after imposing magneticfield, and E moved toward the nega-
corr c corr
tive direction after withdrawing magnetic field. When iron was potentiostatically polarized at the open circuit potential
without magneticfield, a cathodic current wasobserved after imposing magneticfield. An anodic current was detected af-
ter withdrawing magneticfield for iron potentiostatically polarized at the open circuit potential with magnetic field. Mag-
netic fieldinduced cathodic current was larger in acidic solution than in neutral solution, supporting the evidence that mag-
neticfield affected the open circuit state mainly by accelerating the cathodic hydrogen evolution reaction.
Key words: Magnetic field; Iron; Chloride solution; pen circuit state; Potentiostatic polarization; Hydrogen
evolution reaction
HCl NaCl ,
Srivastava ( 0. 07T)
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