电解催化还原.doc

电解催化还原——氯氧化无害化去除水中硝酸盐氮摘要: 基于对Pd － Me 双金属催化还原的机理分析，提出了以NH4+-N为目标产物，Fe 催化还原NO3--N的理论设想．结合折点氯化技术，以Ti/Fe 为阴极，以Ti/Ir － Ru 为阳极，以NaCl 为支持电解质组建无隔膜电解体系，开展了水中NO3--N去除的试验研究．结果表明，利用电解催化还原－氯氧化法可将模拟水样中NO3--N转化为N2去除，其反应历程为阴极催化还原NO3--N生成NH4+-N，阳极电解氯氧化NH4+-N生成N2 . 在ρ(Cl-) 为500 mg/L，电流密度为12 mA/cm2 ，极板距离为9mm，搅拌强度为450 r/min 的试验条件下电解150 min，初始ρ(NO3--N) 为50 mg/L的模拟水样出水ρ(TN) 和ρ(NO3--N) 可分别降至2. 9 和2. 8 mg/L，去除率分别达到94. 1% 和94. 3% ，NH4+-N和NO2--N均未检出．分析认为，阴极对NO3--N的催化还原机理为:Fe 化学吸附氮氧化合物离子中的O 形成固定的N—O 键，电解产生的活性还原物质攻击N—O形成N—H新键． 关键词: NO3--N;催化还原;电解; NH4+-N;氯氧化 中图分类号: X505 文献标志码: A 文章编号: 1001-6929(2011)05-0533-07 Harmless Removal of Nitrate-N in Water by Electrolysis Catalytic Reduction-Chlorine Oxidization HU Xiao-min1 ，YE Shu-fan1 ，HE Ying-dian1 ，ZHANG Yang2 Abstract: Based on analyzing the mechanism of the Pd-Me bimetal catalytic reduction，a theoretical assumption of reducing nitrate-N by Fe catalysis was presented， taking ammonia-N as the target product．Combined with break point chlorination technology，an experimental study was carried out on nitrate-N removal in water based on a septum-free electrolysis system，with Ti/Fe as the cathode，TiIr-Ru as the anode and NaCl as the supporting electrolyte． The results showed that nitrate-N in the simulated water could be removed by transfer into nitrogen through the electrolysis catalytic reduction-chlorine oxidization method．The reaction course was as follows: nitrate-N was catalytically reduced to ammonia-N in the cathode，and ammonia-N was oxidized to nitrogen in the anode by electrolyzing chlorine． For simulation water with 50 mg/L initial nitrate-N，after 150 min electrolyzing at Cl － mass concentration of 500 mg/L，current density of 12 mAcm2 ，plate distance of 9 mm and stirring intensity of 450 r/min，the total nitrogen and nitrate-N concentrations decreased to 2. 9 mg/L and 2. 8 mg/L，respectively，which represented removal rates of 94. 1% and 94. 3% ，respectively． In addition，ammonia-N and nitrite-N were not detected．The mechanism of nitrate-N reduc