共吸附剂修饰TiO2电极及其在染料敏化太阳电池中的应用.PDF

2010 年第68 卷 化 学 学 报 Vol. 68, 2010 第14 期, 1357～1362 ACTA CHIMICA SINICA No. 14, 1357～1362 ·研究论文· 共吸附剂修饰TiO2 电极及其在染料敏化太阳电池中的应用 李 洁 孔凡太 张昌能 刘伟庆 戴松元* ( 中国科学院新型薄膜太阳电池重点实验室 中国科学院等离子体物理研究所 合肥 230031) 摘要 在染料敏化太阳电池中, 引入共吸附剂通常有抑制染料聚集和提高电池性能的作用. 通过光谱电化学、线性伏 安扫描和电化学阻抗谱(EIS)研究了几种以单羧酸基为吸附基团的共吸附剂对纳米 TiO2 薄膜的修饰作用. 结果表明本 实验中的共吸附剂均能使TiO 平带电势负移, 并抑制TiO 导带电子的复合, 其中胆酸类共吸附剂表现出较好的暗电流 2 2 抑制性能. 适当浓度共吸附剂的引入能够提高N719 染料敏化太阳电池的开路电压、填充因子和光电转换效率. 关键词 共吸附剂; 太阳电池; 表面修饰; 染料敏化; 光谱电化学 Coadsorbent Modified TiO Electrode and Its Application in 2 Dye-Sensitized Solar Cells Li, Jie Kong, Fantai Zhang, Changneng Liu, Weiqing Dai, Songyuan* (Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031) Abstract In dye-sensitized solar cell, the introduction of coadsorbents are supposed to suppress the dye-aggregation and improve the performance of the cell. In the study, the surface modification of nanocrystalline TiO2 electrode by coadsorbents with one carboxylate acid as adsorption group have been studied by the methods such as spectroelectrochemistry, linear sweep voltammetry and electrical impedance spectrum (EIS). The results demonstrate that the flat-band potential of TiO2 film shifts negatively and the recombination of the TiO2 conduction band electrons with the electron acceptors in the elect