矽含量对铁矽碳三元合金高温氧化之影响.PDF

矽含量對鐵矽碳三元合金高溫氧化之影響 防蝕工程　第二十二卷第一期　第31 ～ 40 頁　2008 年3 月 Journal of Chinese Corrosion Engineering, Vol. 22, No. 1, pp. 31 ~ 40 (2008) 何日新、謝心心、開物* 、梁哲誌、黃榮潭 Effect of Si-content on the High-Temperature Oxidation of Fe-Si-C Ternary Alloys in Dry Air T. H. Ho, H. H. Hsieh, W. Kai*, G. Z. Liang, R.T. Huang 本研究探討含三種不同矽含量(1, 3, 6Si)之鐵矽碳三元合金，在600 ~ 1000 °C 空氣下 之氧化行為。研究結果顯示，三種合金之氧化動力學呈現不規則趨勢，但氧化增重變化量 皆隨溫度上升而增加；然而 6Si 合金之抗氧化性明顯優於其他合金。氧化後，三種合金主 要生成氧化鐵(Fe O /Fe O ) ，並在氧化物內層有氧化鐵矽(Fe SiO )或氧化矽的富集區域生 2 3 3 4 2 4 成。 關鍵詞：鐵基合金；矽含量；高溫氧化。 ABSTRACT Effect of Si-content on the oxidation of three Fe-Si-C alloys containing 1Si, 3Si and 6Si was studied in dry air at 600 ~ 1000 °C. The oxidation kinetics generally revealed complex and irregular in all cases, although the overall weight-gain data increased with increasing temperature. It was found that the 6Si-alloy exhibits the superior oxidation-resistance, as compared to the lower Si-content alloys. The scales formed on all alloys were composed of mostly Fe O /Fe O , while 2 3 3 4 minor amounts of Fe SiO - or SiO - enriched zone were observed in the scale/substrate interface. 2 4 2 Keywords: Fe-base alloy; Silicon-content; High-temperature oxidation. ˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍˍ 國立臺灣海洋大學材料工程研究所 Institute of Materials Engineering, National Taiwan Ocean University * 連絡作者：wkai@mail.ntou.edu.tw