多重浸提法测定土壤溶液中溶解性气体.docVIP

温带溶解性N2O和CO2含量及其影响机制(刘子锐徐星凯黄耀韩琳韩士杰南京农业大学资源与环境科学学院, 南京 210095中国科学院大气物理研究所大气边界层物理和大气化学国家重点实验室, 北京 100029中国科学院沈阳应用生态研究所, 沈阳 110016 摘 要 利用陶瓷头土壤溶液收集器采集2006年7月至2007年8月间长白山阔叶红松林不同深度(15和60cm)土壤溶液，探讨应用萃取平衡法测定森林土壤溶液中溶解性气体N2O和CO2浓度的可行性，并利用此方法研究林地不同深度土壤溶液中气体影响机理。对于测定林地不同深度土壤溶液N2O和CO2含量均有好的适用性观测期内15cm和60cm溶液溶解性CO2浓度的变化范围分别-10.71 和3.3-6.16 μg CO2-C ml-1，溶解性N2O浓度变化范围分别为-13.40和-27.98 ng N2O-N ml-1。阔叶红松土壤溶液溶解性CO2和N2O浓度呈现出明显的季节性变化。春降水促进土壤溶液溶解性N2O，尤其是60cm溶液CO2浓度的植物生长旺季。分析显示，不同深度溶液溶解性CO2浓度溶解性N2O浓度阔叶红松土壤溶液溶解性CO2和N2O土壤溶液 二氧化碳 氧化亚氮 萃取 森林土壤S158.3 文献标识码 A Dissolved N2O and CO2 concentrations in soil solution under a temperate old-growth forest and their associated mechanisms Liu Zi-rui1,2, Xu Xing-kai2, Huang Yao2, Han Lin2,3, Luo Xian-bao2,3, and Han Shi-jie4 1 College of Resources and Environmental Sciences, Nanjing Agriculture University, Nanjing 210095 2 State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029 3 Graduate University of Chinese Academy of Sciences, Beijing 100049 4 Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016 Abstract Soil solutions at 15 cm and 60 cm depths under a Korean pine and broadleaf mixed natural forest stand at Changbai mountain, northeast China, were sampled by using porous ceramic suction cups during the period from July 2006 to August 2007, to study the dynamics of dissolved N2O and CO2 concentrations in solution and the key associated driving mechanisms. The combination of multiple phase equilibration procedure and gas chromatograph was used for measurement of dissolved N2O and CO2 concentrations of solution. The actual concentrations of both dissolved gases in soil solution could be obtained by the continual three phase equilibration method. During the period of sampling, the concentrations of dissolved CO2 in soil solution at 15 cm and 60 cm depths ranged from 5.26 to 10.71 and from 3.13 to 6.16 μg C