KMnO4引发魔芋粉-丙烯腈的接枝共聚反应GraftCopolymerizationof.PDFVIP

DOI: 10. 15952 /j .cnki .cjsc.2003.04.011 　　　　　　　　 　 Chinese Journal of Synthetic Che istry — 327— KMnO4 引发魔芋粉- 丙烯腈的接枝共聚反应 田大听 (, 　445000) : KM nO4 。、、 、、、,。 　　: ; ; KMnO ; 4 : O636. 1 : A : 1005-1511(2003)04-0327-04 Graft Copolymerization of Konjac Glucomannan- Acrylonitrile Initiated by KMnO4 TIAN Da-ting ( Depart ent of Che ical Engineering, Hubei Institute for Nationalities, Enshi 445000, China) Abstract The graft copoly erization of acrylonitrile AN onto konjac gluco annan KGM: ( ) ( ) 4 . was studied using KMnO as an initiator The influences of poly erization conditions such as preoxidation ti eof KGM, initiator concentration, ono er concentration, H2 SO4 concentra- tion, reaction te perature, reaction ti e and adding sequence of reactants on the graft effi- ciency of the graft copoly erization and the conversion of AN wereinvestigated The echa-. nis of the graft coply erization was also disscussed. Keywords: konjac gluco annan; acrylonitrile; KMnO4 ; graft copoly erizateon 　　 Ce4+ ,, [4,5] 。 、。 , (Ⅲ ), :、、、 KMnO4 /, 、。 , 、。 4 [6] 。 , KMnO ,, D- ,, - 1. 0∶1. 6 D , ,β-1,4- 。 。、、、 [1] 1　 。 , 1. 1　原料 4+ [2, 3] , Ce , : 2003-03-10