柠檬酸法制备BiNbO4陶瓷及其相变和介电性能研究.pdfVIP

Material Sciences 材料科学, 2017, 7(2), 149-155 Published Online March 2017 in Hans. /journal/ms /10.12677/ms.2017.72019 The Phase Transition and Dielectric Performance of BiNbO4 Ceramics Prepared by a Citrate Method 1,2* 1 1 1 1 1 1 Haifa Zhai , Panpan Zhang , Dandan Shi , Yixiao He , Jien Yang , Hairui Liu , Zhiyong Liu 1 Henan Province Key Laboratory of Photovoltaic Materials, College of Physics and Electronic Engineering, Henan Normal University, Xinxiang Henan 2 National Laboratory of Solid State Microstructures, Nanjing University, Nanjing Jiangsu rd th th Received: Mar. 3 , 2017; accepted: Mar. 26 , 2017; published: Mar. 29 , 2017 Abstract BiNbO4 have been successfully prepared by a citrate method using home-made water-soluble Nb-citrate-peroxide. Pure β-BiNbO4 powders are obtained at 700˚C and 1050˚C respectively, and observed the abnormal phase transition from low temperature βto αphase. Compared to BiNbO4 powders, the ceramic samples have residual Bi Nb O phase under the same calcination condi- 5 3 15 tion, which results in the existence of pores and locally abnormal grain growth in ceramics. The ceramics calcined at 1000˚C and 1050˚C have denser structures and smaller change of dielectric performance versus frequency and temperature. The dielectric permittivity and dielectric loss of BiNbO4 ceramics calcined at 1000˚Cand 1050˚Care 44, 0.026 and 35, 0.018 at 1 MHz respectively. Keywords Citrate Method, BiNbO , Phase Transition, Dielectric Performance