碳纳米管-二氧化锰复合材料.pdfVIP

Analytica Chimica Acta 674 (2010) 20–26 Contents lists available at ScienceDirect Analytica Chimica Acta j o u rn al h omepage: w w w. elsev /locate/aca A highly sensitive hydrogen peroxide amperometric sensor based on MnO2-modified vertically aligned multiwalled carbon nanotubes Bin Xu, Min-Ling Ye, Yu-Xiang Yu, Wei-De Zhang ∗ Nano Science Research Center, School of Chemistry and Chemical Engineering, South China University of Technology, 381 Wushan Road, Guangzhou 510640, Guangdong, People’s Republic of China a r t i c l e i n f o a b s t r a c t Article history: In this report, a highly sensitive amperometric sensor based on MnO2 -modified vertically aligned multi- Received 13 April 2010 walled carbon nanotubes (MnO /VACNTs) for determination of hydrogen peroxide (H O ) was fabricated 2 2 2 Received in revised form 2 June 2010 by electrodeposition. The morphology of the nanocomposite was characterized by scanning electron Accepted 3 June 2010 microscopy, energy-dispersive X-ray spectrometer and X-ray diffraction. Cyclic voltammetry, chronoam- Available online 12 June 2010 perometry and electrochemical impedance spectroscopy were applied to investigate the electrochemical properties of the MnO2 /VACNTs nanocomposite electrode. The mechanism for the electr