生物质燃料催化氧化燃烧新工艺研究.docVIP

毕业设计论文 生物质燃料催化氧化燃烧新工艺研究 摘 要 将生物质作为燃料使用，是可再生能源的有效利用途径。然而直接燃烧的办法存在操作条件复杂、燃烧不充分等缺点。使用固相催化的办法，是一种新的途径。 本课题采用初步热失重分析法，分别测定了MnO2，Fe2O3，KMnO4三种催化剂在不同温度下与不同生物质燃料锯末、玉米秸秆混合燃烧时，燃烧前后生物质燃料质量的变化。采用热重分析法，对锯末这种生物质燃料以空气为氧化剂及以MnO2为催化剂的燃烧过程进行了对比研究。采用X射线衍射分析法，对MnO2未燃烧、单独燃烧及作为催化剂燃烧三种状态进行了定性相分析。 结果表明，相同试验条件下MnO2催化效果相对好，是较好的催化剂。以锯末为生物质燃料，添加MnO2能显著改善生物质燃料的燃烧性能，降低生物质燃料的着火温度，提高生物质燃料的燃烧速度，使生物质燃料的燃烧过程更集中。未经煅烧的MnO2中可能含有Mn、gamma- MnO2、epsilon- MnO2。经高温煅烧后，MnO2被还原为Mn3O4，其自身起到氧化剂的作用，有助于生物质燃料的燃烧。当MnO2与生物质燃料混合燃烧时，其自身的燃烧程度相对其单独燃烧时更充分。 关键词：生物质燃料，催化剂，热重分析，X射线衍射分析  NEW TECHNOLOGY OF BIOMASS FUEL COMBUSTION BY CATALYST ABSTRACT It is an effective way of using renewable energy to use biomass as fuel. However, there are some disadvantages, such as complex operating conditions and inadequate combustion in the direct-burning method. The use of solid catalyst is a new way. In this thesis, primary thermogravimetic analysis has been used to determine the change of biomass fuel sawdust and straw which burning with catalysts of MnO2, Fe2O3 and KMnO4 at different temperatures. Thermogravimetic analysis has been used to research and compare the different combustion processes of sawdust burning with air and MnO2. X-ray diffraction analysis has been used to do qualitative analysis of MnO2 when it is not burning, burning solely, and burning as catalyst. The results show that, the catalytic effect of MnO2 is better than the other, and it is a good catalyst. Biomass fuel sawdust combust with MnO2 can significantly improve the combustion performance of biomass fuel. Also, sawdust combust with MnO2 can reduce the ignition temperature of biomass fuel and make the combustion process more focused. MnO2 which is not burning may contain Mn, gamma-MnO2, epsilon-MnO2. After combustion at high temperature, MnO2 is deoxidized to Mn3O4. At the same time, MnO2 plays the role of oxidant and help biomass fuel to burning. MnO2 burning more fully when it combust with biomass fuel than it burning solely. KEY WORDS: biomass fuel, cata