不干胶废弃物热解特性研究 - 环境工程学报.doc

不干胶废弃物热解与燃烧动力学特性(（修改稿） 付兴民1，徐国欢1，杨 迪12，贾晋炜1，鲁明元1，舒新前1 1中国矿业大学北京化学与环境工程学院北京100083 2. 太原市市容环境卫生科学研究所山西 太原030002 摘 要： 关键词: 不干胶废弃物；热解；燃烧；表观活化能 中图分类号：TK09，X705，X796 文献标识码：A Characteristics of pyrolysis and combustion of pressure sensitive adhesives wastes Fu Xingmin1, Xu Guohuan1, Li Zijun1, Ren Shanpu1, Di Yang1, 2, Jia Jinwei1, Lu mingyuan1, Shu Xinqian1 (1.School of Chemical and Environmental Engineering, China University of Mining and Technology University, Beijing, 100083, China; 2. Taiyuan environmental sanitation research institute, Taiyuan, 030002) Abstract: The pyrolysis and combustion characteristics of pressure sensitive adhesives wastes (PSAs) were investigated by thermal gravimetric analysis under nitrogen and air atmosphere, moreover, the kinetics parameters of PSAs pyrolysis and combustion both were calculated using Doyle method. The results indicated that there depicted similar between the pyrolysis and combustion of PSAs. However, there existed three weightloss peaks during pyrolysis and two peaks in combustion for temperatures of 300℃~600℃.The kinetics results showed that the process of PSAs pyrolysis consisted of multi-stage cracking reactions, which could be described as four first-order reactions; the apparent activation energy in the first peak scale decreased, while in the second peak scale, the third peak scale of the pyrolysis and the fourth peak scale of the semi-coke cracking stage increased with the rising of heating rate. PSAs combustion could be described as three first-order reactions, in which the apparent activation energy decreased with the increase of heating rate. What’ more, the apparent activation energies in combustion exhibited lower than those in pyrolysis. Keywords: pressure-sensitive adhesive wastes (PSAs); pyrolysis; combustion; the apparent activation energy 不干胶亦可称为自粘标签材料，是以纸张、薄膜或特种材料为面料，背面涂有胶粘剂，以涂硅保护纸为底纸的一种复合材料。随国民经济的发展，不干胶类产品在食品、日化、医药、物流等行业得到高速增长，其需求量以近20%比率快速增长，2012年我国标签印刷产量已达到34亿平方米[1]。同时不干胶类废弃物（pressure-sensitive a