过氧化尿素的合成研究-山西职业技术学院.PDFVIP

( ) 22 2 Journal of Shanx iNormalUn iver ity V ol. 22 No. 2 2008 6 N atural Science Ed ition June. 2008 : 1009-4490( 2008) 02-0058-05 1 2 2 2 2 , , , , ( 11 , 030006; 21 , 030024) : , , , , , 94. 19 % , 18. 79% . : ; ; ; : O6 111 62 : A 0 ( U rea Perox ide) , UP, , , CO( NH ) # H O , 94. 08, , , 2 2 2 2 [ 1] . , , , . , , , , . , 5% pH 6~ 7. , [ 2] . . , [ 3] , , 60 % , [ 4] 95% 99. 5 %; 85% 98% 99. 5% . , , . , ( 10% ~ 20% ) , [ 5 ] 17 t~ 43 t. . , , , , , , . 1 1. 1 , 30 % , , , , N aH PO # 2H O, Span-80, PE-400, Tw een-20, 2 4 2 Tw een-40, Tween-60, . : 2008-03-18 : ( 1967) ), , , , , . 2 , : # 59# 1. 2 H O + CO (NH ) y CO( NH ) # H O 2 2 2 2 2 2 2 2 1. 3 30 % H O , , 2 2 , - 5 e , , . KM nO . 4 1: 1 Fig. 1 T he flow chart of the preparation proce of the urea perox ide 2 2. 1 N aH PO , 40e , 40 m in, 2 4 , 1. 1 T ab1 1 T he effect of m olar ratio of reactant on yield and active oxygen content in product n () /n () % % R % 1B 1 181 31