ScAlMgO4 晶体的生长缺陷.PDF

第36 卷第5 期 硅 酸 盐 学 报 Vol. 36 ，No. 5 2 0 0 8 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY M a y ，2 0 0 8 ScAlMgO4 晶体的生长缺陷 1,2 1 1 1 唐慧丽 ，董永军 ，徐 军 ，吴 锋 (1. 中国科学院上海光学精密机械研究所，上海 201800 ；2. 中国科学院研究生院，北京 100039) 摘 要：采用提拉法生长出φ30 mm × 55 mm 的ScAlMgO4 晶体。在晶体生长过程中有轻微的挥发，粉末X 射线衍射分析表明：挥发物质为MgO 单 相。运用扫描电镜、光学显微镜以及高分辨 X 射线衍射仪对晶体中的包裹物、开裂、生长条纹和小角晶界缺陷进行了研究。结果表明：温度梯度和 热应力是形成晶体中缺陷的主要原因。通过合理设计温场，控制固–液界面的形状及冷却过程的降温速率，可以提高晶体的完整性。 关键词：铝镁酸钪晶体；提拉法；晶体缺陷 中图分类号：O782 文献标识码：A 文章编号：0454–5648(2008)05–0689–05 GROWTH DEFECTS OF ScAlMgO CRYSTAL 4 1,2 1 1 1 TANG Huili ，DONG Yongjun ，XU Jun ，WU Feng (1. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800; 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China) Abstract: ScAlMgO4 crystal with a diameter of 30 mm and a length of 55 mm was grown by the Czochralski method. There was slight volatilization during the growth process. The powder X-ray diffraction (XRD) pattern reveals that the volatile substance is sin- gle-phase MgO. The defects in the as-grown crystal, including inclusions, cracks, growth striation and small-angle grain boundary were studied by scanning electron microscopy, Leitz optical microscopy and high resolution XRD. The results show that the main origins of the production of defects are axial temperature gradient and thermal stress in crystal. Crystal perfection can be improved by strategicall