同位镀汞阳极溶出伏安法测定牛奶中镉、铅、铜.pdfVIP

※分析检测 自由融事 2014, Vo1.35, No.08 121 同位镀示阳极溶出伏安法测定牛奶中锅、铅、铜 朱浩嘉，潘道东飞顾愿愿，李建龙，赵紫微，丁琳 (宁波大学海洋学院，浙江宁波 31521 1) 摘 要z 建立阳极溶出伏安法同时快速测定牛奶中的锅、铅和铜元素的方法。利用同位镀柔阳极溶出伏安法对 牛奶样品中锅、铅和铜元素含量进行同时测定，并对测试条件进行优化。锅、铅和铜元素峰电位分别为一0.70、 一0.52、一0.08 V，线性范围分别为0.1~40、 1~80、 0.5~1∞μg/L，检测限为0.06、 0.3、 0.1μg儿。采用该方法测 定了牛奶样品中的铺、铅和铜含量，加标国收率分别为99.57%、 101.3 9毛、 98.00% ，相对标准偏差 Cn=5) 分别为 4.0%、 2.9%、 2.7% ，将测定结果与原子吸收光谱法检测结果对比，两者无显著性差异(P0.05) 。结果表明该方法 快速、简单、准确，可用于牛奶中锅、铅和铜元素的同时检测。 关键词:阳极溶出伏安法:牛奶:锅:铅:铜 DetermÏnation of Cadmium, Lead and Copper in Milk by Hg-Plated Anodic Stripping Voltamme位y ZHUHao才ia， PAN Dao-dong* , GU Yuan-yuan , LI Jian-long , ZHAO Zi-wei , DING Lin (School ofMarine Sciences, Ningbo University , Ningbo 315211 , China) Abstract: A method for the simultaneous determination of cadmium, lead and copper in milk was established using Hg-plated anodic stripping voltammetry. Under optimized test conditions , the peak potentials of cadmium, lead and copper were -0.70, -0旦时-0.08 V , respectively. The lineardomain ranges were 0.1-40, 1-80 and 0.5一1 ∞昭L， respectively , and the limits of detection were 0.06, 0.3 and 0.1μg/L，而spectively.ηle spiked recoveries of cadmium, lead and copper were 99.57% , 101.3% and 饵，∞%， respectively , with RSDs (n = 5) of 4.0% , 2.9% and 2.7% , respectively. There was no significant difference (P 0.05) between the results from simultaneous anodic stripping voltamme町and atomic absorption spectroscopy (AAS). This voltantmetric method has the advantages of rapidity , simplicity and accuracy , and can be used for the simultaneous determination of cadmium, lead and copper in milk. Key words: anodic stripping voltammetry; milk; cadmium; lead; copper 中图分类号: TS20 1.2 文献标志码:A