DSC简介.ppt

热分析 ——原理及其在聚合物研究中的应用 热分析 (Thermal Analysis) 热分析技术的概述 差示扫描量热法（DSC）在高分子研究中的应用 示差扫描量热法 DSC与DTA测定原理的不同 影响DSC实验结果的因素 扫描速率 试样用量 试样粒度 气氛 扫描速率 扫描速率 研究实例 试样用量 对测试结果的影响同扫描速率的影规律相似 试样用量 试样用量 研究实例 试样粒度 粒度越大 热阻越大 特征温度及熔融热焓越低。 气氛 为避免氧化的发生，一般采用惰性气体 如N2、Ar、He等 DSC在高分子研究中的应用 各种转变温度的测定 DSC在高分子研究中的应用 各种转变温度的测定 各种转变温度的测定 DSC在高分子研究中的应用 各种转变温度的测定 结晶速率及其动力学分析 DSC在高分子研究中的应用 各种转变温度的测定 Miscibility study Miscibility study Effect of blend composition on the spherulitic morphology of PVDF Effect of blend composition on the spherulitic growth rates of PVDF Effect of blend composition on the spherulitic growth rates of PVDF Crystallization kinetic parameters of PVDF in the PVDF-Rich Blends Crystalline morphology of PBSA Crystalline morphology of PBSA Crystallization kinetic parameters of PBSA for the PBSA-Rich Blends Effects of blend composition and crystallization temperatures on the overall crystallization rate of PBSA Conclusions Conclusions Plots of crystallization peak temperature Tp as A function of cooling rate for PBSU/PVPh blend. Plots of crystallization peak temperature Tp against log ? for PBSU/PVPh blend. Plots of relative crystallinity against crystallization temperature for neat PBSU during nonisothermal melt crystallization. Plots of relative crystallinity against crystallization time for PBSU/PVPh 80/20 during nonisothermal melt crystallization. Avrami plots of PBSU/PVPh blend during nonisothermal melt crystallization; (a) neat PBSU and (b) PBSU/PVPh 80/20. (a) (b) Nonisothermal Crystallization Kinetics Parameters from the Avrami Method for Neat and Blended PBSU The aim of the present study is to gain a better understanding of semicrystalline/semicrystalline polymer mixtures and to establish to what extent the current knowledge of polymer blends applies to these complex systems. Research aims The PVF2 sample used in this study (Mw =140 000) was supplied by Polysciences Inc. The PBA sample (Mw =14 050) was obtained from Scientific Polymer Products, Inc.