MmNi5-基储氢合金扫描电镜能谱仪定量分析.pdfVIP

电子显微学报990214 电子显微学报 1999年 第2期 第18卷 Vol.18 No.2 1999 MmNi-基储氢合金扫描电镜能谱仪定量分析 5 孙丽虹　王瑞坤　刘安生　王超群 李　灏　靳红梅　张昭良　李国勋 　　摘　要： 使用配备EDS的SEM，研究了MmNi 5-基储氢合金的微观组织和微区成 分。研究的合金中稀土元素含量低于化学比，晶界有Co,Mn和Al富集相析出。分别使 用ReB、RePO 和纯稀土金属作为分析稀土元素的标样进行定量分析。结果表明，全 6 5 14 部采用纯金属标样(包括纯稀土金属标样)分析结果最好；采用ReB 和RePO 作为分析 6 5 14 稀土的标样时，分析误差较大。文章对误差较大的产生原因进行了讨论。 　　关键词： 储氢合金；扫描电镜；能谱仪；微区分析；标样 　　分类号： O766；O656.9　　文献标识码： A Quantitative analysis for MmNi -based hydrogen 5 storage alloy by using SEM equipped with EDS SUN Li-hong WANG Rui-kun LIU An-sheng WANG Chao-qun LI Hao JIN Hong-mei ZAHNG Zhao-liang LI Guo-xun (General Research Institute for Non-Ferrous Metals,Beijing 100088,China.) 　　Abstract: The microstructure and micro-area composition of the MmNi -based 5 hydrogen storage alloy was studied by using SEM equipped with EDS.In the alloy studied in present paper,the mischmetal content is lower than the stoichiometrical composition,and some elements such as Co and Ni or Al-rich phase precipitation have occurred at the grain boundaries.The standard samples used for the quantitative analysis were ReB ,ReP O and 6 5 14 pure rare earth elements respectively.In order to quantitatively analyzing the content of rare element in the about alloy,the best results can be obtained by using the standard sample of pure metals.The bigger error arised from using ReB or ReP O as the standard samples