Mo 添加量对纳米改性金属陶瓷显微组织的影响 - 矿冶工程.PDF

25 2 矿　冶　工　程 Vol.25 №2 2005 04 MINING AND METALLURGICAL ENGINEERING April 2005 ① Mo 许育东, 刘　宁, 石　敏, 韩成良, 晁　晟 ( , 230009) 　:Mo TiC-TiN(nm)-WC-Mo C-Ni-Co 、。, 2 , /(core/rim structure)。 Mo 。SEM :(), 。 :;; :TG148 :A :0253-6099(2005)02-0077-04 Effects of Mo Addition on Microstructure of Nano Modified Cermets XU u-dong, LIU Ning, SHI Min, HAN Cheng-liang, CHAO Sheng (School of Materia ls S cience and Engineering , Hef ei University of Technology , Hef ei 230009, Anhui, China ) Abstract :A study was made on the effects of Mo addition on the microstructural characteristics, mechanical properties and fractography of nano-TiN modified cermets which are applied to milling tools.The results show that the cermet exhibits a typi- cal two-phasemicrostructure (i.e.metallic phase and ceramic phase embedded in the metallicphase).Theformation of core/ rim structureof the ceramicphase is relevant to the dissolution and deposition mechanism.A small additionof Mo can improve the mechanical properties of the cermets.In addition, a SEM analysis of thefracture surface suggests there is amixture crack- ing mechanism (transgranular failure and intergranular failure), and that themetallic phase has apparent tears. Key words:nano-modification;cermet;microstructural feature 　　,Ti(C,N) ( 、、、 )。,TiN [1～3] [4～5] , WC (、) , , (Al2O3)。Ti(C,N) 。, , TiC-TiN (nm)-WC-Mo C-Ni , Ni-Co 2 , TiN [4～5] 。(TiN ) 。Mo TiC-TiN (nm)-WC- , Mo C