微波消解-氢化物原子荧光光谱法同时测定化妆品中砷和汞.pdfVIP

研究报告 哈二?噎噩噩 微波消解-氢化物原子荧光光谱法同时测定化妆品中呻和宗势 组噩噩 作者简介 张爱平 (1979一) ，男，硕士，工程师 ， 主 南通出入境检验检疫局，江苏南通 226004 妥从事光谱、色谱、电化学等方面的检 ·张爱乎葛红梅王红卫张义国江涛 验和科研工作。 联系电话: 0513 E-mai l:139. com 建立了一种简便、快速、高效的微波消解·氢化物原子荧光光谱法同时测定化妆品中卿和柔的方法。重点探讨了样品前处 理条件、仪器条件、载流溶液介质、预还原剂、还原剂等对试验测定结果的影响。在优化条件下，评价了方法的可靠性. 元素 仰在 0-1 0 ng/mL 浓度范围内具有良好线性关系.线性相关系数(r) 为 0. 9995. 检出限为 0.01 ng/mL.加标回收率在 97. 6% -10 1. 1 %之间. 元素柔在 ()-1 ng/mL 浓度范围内具有良好线性关系，线性相关系数(r) 为 0.9997.检出限为 O. ()6tJ ng/ mL. 加标回收率在 93.7%-98. H %之间。 将方法应用于化妆品中痕量刑和柔的分析，结果令人满意. 锢噩E 微波消解氢化物发生原子荧光光谱法化妆品柔仰 D etermination of Arsenic and Mercury in Cosmetics by Hydride Generation Atom Fluorescence Spectrome- try with Microwave Digestion Method ZHANGAipinK GE Hongm ei WANG HοηKwei ZHANG WenKuo ] IANG Tao (Nantong Entry . Exit Inspect ion and Quarantine Bureau. Nantong 226004. Jiangsu. China) Abstract: A simple. rapid and efficient determination of arsen ic and mercury in cosmetics was performed by hydrid e genera- tion atom fluorescence spectrometry after microwave digestion. The factors relevant to the method including the pretreatment for sample. optimized parameter for the apparatu s. carrying solution. reducing agent in advance and reducing agent , were in- vestigated and optimized. Under the opt imized conditions. th e proposed method provided a good line.arity. for the det ermination of arsenic in the range of 0 to 10 ng/ mL with correlation coefficient of O. 9tJ