结构 立方紧密装填(ccp).PPT

Ch.10 – Metallic bondingCh.10 –金屬鍵 * A.Metallic bonding A. 金屬鍵 Fig. 10-1 B.?? Strength of metallic bond 1. The ________________ is a good measure of the metallic bond strength. melting point B.??金鍵的强度 1. _________是金屬鍵强度的好指標。 溶點 2. Metallic bond strength increases with a)______________________________________ of the metal atom. Table 10-1 increasing number of valence electrons 98 650 660 1 2 3 Sodium 鈉 Magnesium 鎂 Aluminium 鋁 Melting point (oC) Number of valence electrons(s) Metal 2.金屬鍵强度隨以下增加 a)金屬原子的______________增加。 價電子數目 b)___________________of the metal atom. Table 10-2 decreasing size 180 98 64 39 29 0.152 0.186 0.231 0.244 0.262 Lithium 鋰 Sodium 鈉 Potassium 鉀 Rubidium 銣 Caesium 銫 Melting point (oC) Metallic radius (mm) Metal b) 金屬原子的________減少。 大小 C.?? Metallic Crystals In giant metallic structures, there are two types of packing: __________________________and ________________________ close-packed structure open structure C.??金屬晶體 在巨型金屬結構，兩種裝填方式:______________及________。 緊密裝填結構 開放結構 1.? Close-packed structure Arrangements in which the gaps are kept at minimum are called close-packed structure, it can be calculated that ________ of the space is empty. 26% 1.?緊密裝填結構 這個排佈方式所餘的空隙是最小的，可計算出是，_______空間。 26% a) ___________________________________________ l? ‘ababab’ structure. Fig. 10-4, 10.5, 10.6 Hexagonal close-packed (h.c.p.) a) ___________________________________________ l? ‘ababab’結構. 六方緊密裝填結構(h.c.p.) a) ___________________________________________ l? ‘ababab’ structure. Fig. 10-4, 10.5, 10.6 Hexagonal close-packed (h.c.p.) ? l? E.g. Zn, Mg, Rb a) ___________________________________________ l? ‘ababab’結構. 六方緊密裝填結構(h.c.p.) b) __________________________________________________________ l‘abcabc’ structure. Fig. 10.7, 10.8 Cubic close-packed (c.c.p.)/Face-centred cubic (f.c.c.) b) _