锰锌铁氧体废料浸出液定比例还原.PDFVIP

第 39 卷第 5 期 中南大学学报自然科学版( ) Vol.39 No.5 2008 年 10 月 J. Cent. South Univ. (Science and Technology) Oct. 2008 锰锌铁氧体废料浸出液定比例还原 彭长宏，李景芬，陈带军 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：在热力学理论分析的基础上，依据锰锌铁氧体废料硫酸浸液中Fe3+ 的量及铁氧体理论配方，研究利用金 属铁粉、锰粉和锌粉对此浸出液的定比例还原过程。研究结果表明：定比例金属粉末还原技术能有效控制还原液 中Fe ，Mn和Zn 3 种主成分的实际比例符合或接近其理论配方，其质量分数平均相对误差分别为：Fe O ，0.153% ； 2 3 Mn O ，−0.415% ；ZnO ，−0.137%，均控制在锰锌铁氧体制备要求的−2%~2%误差范围之内。定比例还原技术还 3 4 能实现Fe3+ 的完全还原，还原液中Fe3+ 的质量浓度小于0.1 g/L，还原率大于 99.8% 。 关键词：锰锌铁氧体废料；硫酸浸液；还原 中图分类号：X758 文献标识码：A 文章编号：1672−7207(2008)05−0887−04 Proportion reduction in leaching solution of Mn-Zn ferrite wastes PENG Chang-hong, LI Jing-fen, CHEN Dai-jun (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: On the basis of thermodynamics theory, and according to the content of Fe3+ in sulfuric acid leached liquor from waste Mn-Zn ferrite powders and the theoretical prescription of Mn-Zn ferrite, the sulfuric leached liquors’ proportion reduction processes, in which special proportion reducing agents of Fe, Mn and Zn powders were used, were studied. The results show that the proportion reduction technology can effectively control the actual proportion of Fe, Mn and Zn in reduction solution, approaching to the theoretical prescription of Mn-Zn ferrite. The average relative errors of mass fraction are as follows: Fe O , 0.153%; Mn O , −0.415% and ZnO, −0.137%, respectively. And all of them