葛粉掺假的近红外漫反射光谱快速检测 - 噪声与振动控制.pdf

※分析检测 食品科学 2014, Vol.35, No.08 133 葛粉掺假的近红外漫反射光谱快速检测 1 1 1 2 1,3,* 陈 嘉 ，刘 嘉 ，马雅钦 ，祝诗平 ，赵国华 （1.西南大学食品科学学院，重庆 400715 ；2.西南大学工程技术学院，重庆 400715 ； 3.重庆市农产品加工技术重点实验室，重庆 400715 ） 摘  要：研究葛粉中掺假红薯淀粉和马铃薯淀粉的近红外漫反射光谱快速检测方法。采集样品的近红外漫反射光 谱，采用主成分回归和偏最小二乘法建立校正模型，并对比光谱预处理方法和光谱建模区间对模型的影响。结果表 明，采用偏最小二乘法建模，光谱采用标准正态变量变换预处理，光谱区间选择在962～1 389 nm时，模型预测效 2 果最佳，外部验证预测相关系数（RP ）达0.994 5 ，均方根误差2.298 7% ，相对分析误差13.56，平均回收率99.89% n （=9，RSD=2.96% ），这表明近红外漫反射技术能对葛粉中掺假红薯淀粉和马铃薯淀粉进行有效检测。 关键词：近红外漫反射光谱；葛粉；掺假；快速检测 Rapid Detection of Kudzu Starch Adulteration by Near-Infrared Diffuse Reflectance Spectroscopy 1 1 1 2 1,3,* CHEN Jia , LIU Jia , MA Ya-qin , ZHU Shi-ping , ZHAO Guo-hua (1. College of Food Science, Southwest University, Chongqing 400715, China; 2. College of Engineering and Technology, Southwest University, Chongqing 400715, China; 3. Chongqing Key Laboratory of Agricultural Product Processing, Chongqing 400715, China) Abstract: Near-infrared diffuse reflectance (NIDR) spectroscopy combined with chemometric techniques was developed for rapid detection of kudzu starch adulterated with cheaper starches (potato and sweet potato starch). Principal component regression (PCR) and partial least squares regression (PLSR) were used to build and evaluate calibration models by different pre-treatment methods and at different wavelength bands . The PLS calibration model based on wavelength bands of 962– 1 389 nm