超亲油——超疏油.pptx

A brife introduction about super oleophobic surface;来自大自然的灵感？;人们受这些生物的启发， 通过构筑微纳复合结构以及修饰低表面能物质， 制备了一系列具有自清洁效应的超疏水表面,并在织物 建筑物表面和车窗玻璃等领域得到广泛应用。但超疏油表面( 对油的接触角大于 150°) 的制备一直是一个难题;理由:;解决办法;;the remarkable oil-repellent ability of ?sh scales, whichallows ?sh to survive in oil-polluted water;什么是水下超疏油表面;鱼鳞化学组成是亲水性的羟基磷灰石 蛋白质和一层薄薄的黏液 在空气中，鱼体表是超亲油的， 而在水下却表现出超疏油的性质， 对油的接触角为( 156. 4 ± 3. 0) ° 对比其在空气中超亲油和水下超疏油的特点， 我们认为对于浸润性的转变， 水相起到关键的作用;Fig. 1 Surface structures of fish scales and biomimic PAM hydrogel surface: ( a) optical image of the fish scales，( b ～ c) SEM images of fishscales at low and high magnifications and ( d ) PAM hydrogel film with fish- scale structures ( The inserts are oil droplet on the surfaceunderwater and high magnification image． ) ( Reproduced from Ref， with permission from Wiley- VCH); 我们认为对于浸润性的转变， 水相起到关键的作用． 当油滴接触到水中的鱼体表面时， 水分子陷入亲水的鱼体表面的微纳米结构中， 对油滴产生排斥， 形成了油/水/固的复合界面， 从而形成了超疏油的性质;Fig. 2 ( a ～ c) SEM images of the substrates and shapes of oil droplets taken at different stages duringnormal adhesive force measurement process on different substrates: on the ( a ) smooth，( b )microstructured and ( c ) micro / nanostructured silicon substrates; Diagrams illustrating the effect ofsurface structure on the wetting behaviors of solid substrates in oil /water / solid three- phase systems: Aliquid 1 droplet on ;( d ) smooth surface，( e ) microstructured surface and ( f ) micro / nanostructuredsurface in a liquid 2 phase ( Reproduced from Ref．［18］， with permission from Wiley- VCH);微纳复合的粗糙结构;总的来讲—— 亲水性的化学组成和微纳复合的粗糙结构是设计水下超疏油表面的关键因素;Preparation and characterization of a surface with switchable superoleophilicity and superoleophobicity on a non-woven textile substrate. (a) Schematic showing the preparation strategy for a surface with switchable superoleophilicity and superoleophobicity on a non-woven textile. (b) Scanning electron microscope (SEM) image of the raw textile. Inset: enlarged view of the surface of a single ?ber. (c) SEM image of the texti