多相操作均相催化剂研究技术的现代发展.pdfVIP

2007年12月 Dec．2007 第15卷 第12期 工业催化 INDUSTRIAL CATALYSIS Vo1．15 No．12 多相操作均相催化剂研究技术的现代发展 黄仲涛，张美英 (华南理工大学，广东广州510640) 摘 要：综述了多相操作均相催化技术的研究进展，分成水相一有机相、有机相一有机相、全氟相溶 剂对、超临界流体相、非水离子液体溶剂相和可溶态聚合物相等组成的两相操作均相催化体系。重 点评述了水相／有机相两相体系。水相一有机相两相体系率先使得多相操作均相催化技术获得突 破，并且取得工业化应用成就，也是目前最受工业界和学术界关注的领域。 关键词：多相操作；均相催化剂；水相一有机相；有机相一有机相 中图分类号：0643．3 文献标识码：A 文章编号：1008．1143(2007)12-0001-09 Modern development of multiphasie homogenous catalyzed technology HUANG Zhongtao，ZHANG Meiying (South China University of Technology，Guangzhou 510640，Guangdong，China) Abstract：Internationally，all homogenous catalyzed technologies in muhiphase operation were developed very quickly during recent twenty years．The development was reviewed in this paper．All the realistic possibilities described SO far using muhiphase operation of homogeneous catalysis：processes with aque- OUS-organic，organic-organic，fluorous solvent pairs，nonaqueous ionic solvents，supercritical fluids and systems with soluble polymers were reviewed．The development of aqueous—organic biphase catalysis had received much attention．It was no wonder that the impressive advantages and the tremendous progress of the biphase processes were first used commercially with aqueous-organic phase operation．Other multi- phase operation processes were no more further discussed in detail． Key words：muhiphase operation；homogeneous catalyst；aqueous—organic phase；organic-organic phase CLC number：0643．3 Document code：A Article ID：1008-1143(2007)12-0001-09 随着科学与技术的快速发展，近年来均相催化 巨大意义。 剂有了显著的进展。集中表现在均相催化剂的修饰 图1中，水相催化剂溶液与反应物A与B一起 和操作方法，在催化剂反应中，免除了催化剂的脱 进入反应器，反应生成产物C和D