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32 　 6 　　　 Vol.32, No.6 2002 　　12 BATTERY　BIMONTHLY Dec., 2002 　 1 2 1 1 1 左晓希, 刘建生, 李伟善, 南俊民,袁中直 (1.华南师范大学化学系, 广东 广州510631;2.广州 色金属研究院, 广东 广州510651) :介绍了含硼化合物在二次锂离子电池电解质中的应用。B O 和烷基或烷氧基硼氧烷作添加剂加入到电解质中, 可 2 3 减少电池在循环中放电容量的衰减, 提高电池的循环寿命,但同时也增加了电池在初次充放电时不可逆容量的损失。某些 含硼氧环的化合物加入到聚合物电解质中,能提高电解质中锂离子的迁移数及减少电极表面的电阻。硼酸酯的熔点低、沸 点高, 以它作溶剂, 能提高电解质的高低温性能及电化学稳定性。以含 较大阴离子的 机锂盐作溶质, 可提高电解质的 电化学窗口和电导率。 :含硼化合物;　锂离子电池;　电解质 :TM912.9 　　:B　　:1001-1579(2002)06-0358-03 Application of boron compounds to electrolyte of Li-ion battery 1 2 1 1 1 ZUO Xiao-xi , LIU Jian-sheng , LI Wei-shan , NAN J n-min ,YUAN Zhong-zhi (1.Dep ar tmen t of Chem istry , S ou th China Norm a l Un iversity , Guangz hou, Guang dong 510631, China ; 2.Guangz hou R esearch I nstitu te of Nonf errous Meta ls, Guangz hou, Guangdong 510651, China ) Abstract:The application of some boron compo nds to Li-ion batteries as solvents, sol tes and additives in electrolyte was intro- d ced.The electrolytes which contained B O or compo nd with a (BO)ring co ld red ce the loss of capacity d ring cycling and improve 2 3 3 the cycliability of Li ion batteries, b t also increased the irreversible capacity loss d ring the first cycle.In polymer electrolytes,the addition of compo nds containing (BO)ring co ld improve Li+ transference n mber and red ce resistance between electrode and elec- 3 trolyte.Bora