第一章第4节土壤吸附-解析研究实例.ppt

第4节土壤吸附-解析研究实例 重金属在土壤中的吸附-解析 农药在土壤中的吸附 土壤吸附-解析的影响因素研究 图1 模拟酸雨影响下黄泥土对铜的吸附曲线Fig.1 Effect of acid rain on Cu adsorption isotherm of Huangnitu 图2 模拟酸雨影响下白土对铜的吸附曲线Fig.2 Effect of acid rain on Cu adsorption isotherm of Baitu 图3 模拟酸雨影响下乌泥土对铜的吸附曲线Fig.3 Effect of acid rain on Cu adsorption isotherm of Wunitu 表2不同土壤吸附等温线拟和参数Table2 Effect of acid rain on the paramenter of Cu adsorption isotherm of three soils 图4 模拟酸雨影响下黄泥土易解吸态铜的解吸曲线Fig.4 Effect of acid rain on the desorption curves of easily desorped Cu in Huannitu 图5 模拟酸雨影响下白土易解吸态铜的解吸曲线Fig.5 Effect of acid rain on the desorption curves of easily desorped Cu in Baitu 图6 模拟酸雨影响下乌泥土易解吸态铜的解吸曲线Fig.6 Effect of acid rain on the desorption curves of easily desorped Cu in Wunitu 图7 模拟酸雨影响下黄泥土难解吸态铜的解吸曲线Fig. 7 Effect of acid rain on the desorption curves of difficultly desorped Cu in Huannitu 图8 模拟酸雨影响下白土难解吸态铜的解吸曲线Fig. 8 Effect of acid rain on the desorption curves of difficultly desorped Cu in Baitu 图9模拟酸雨影响下乌泥土难解吸态铜的解吸曲线 Fig. 9 Effect of acid rain on the desorption curves of difficultly desorped Cu in Wunitu 表3模拟酸雨影响下解吸态铜（Y）与铜吸附量(X)的关系拟合参数Table3 Effect of acid rain on the relationship between easily and difficulty desorption Cu(Y) and Cu adsorption (X) 表4模拟酸雨影响下土壤吸附解吸拟合参数相对值汇总表Table4 Effect of acid rain on the relationship between easily and difficulty desorption Cu(Y) and Cu adsorption (X) 除草剂胺苯磺隆在土壤中的吸附 2、土壤有机质含量的影响 3、土壤粘粒含量的影响 4、土壤pH的影响 结论 胺苯磺隆在3 种不同类型土壤上的吸附情况能很好地与Freundlich等温吸附方程相吻合，且胺苯磺隆在土壤中的吸附强弱顺序为：红壤，潜山水稻土，宣城水稻土 黄褐土，黄潮土，砂姜黑土。 土壤的理化性质对胺苯磺隆的吸附有重要影响，土壤吸附常数Kf与土壤有机质、粘粒含量呈正相关，与土壤 值pH呈负相关，与土壤阳离子交换量相关性不明显。 * * 表1供试土壤的基本性质 Table1 Basic properties of soils studied 一、土壤对重金属的吸附-解吸 除草剂，主要除单双子叶杂草 1.胺苯磺隆的吸附等温线 Kf越大代表吸附能力越强。 K=0.1688organics+0.9883 r2=0.8393P0.05) K f =11.82clay%-4.71212 r2=0.8665，P0.05) K f =10.005-0.9992 pH r2=0.937，P0.05)