物化法和o3氧化法对vb12废水脱色处理的研究 - 环境工程学报.doc

拟再审修改稿O3氧化法对维生素B12废水脱色处理的研究 单思行1，范鹏飞2，邢奕2，谯耕2 (1吉林大学环境与资源学院，长春 130026； 2北京科技大学土木与环境工程学院，北京 100083) 摘要：采用改性矿物吸附法和O3氧化法对某制药厂维生素B12废水进行脱色处理。以废水色度去除率大于50%为目的，通过实验确定改性矿物吸附法和O3氧化法处理维生素B12废水的最佳工艺条件。结果表明，改性矿物吸附法的最佳条件为：废水的pH值为3.00，有机化膨润土的投加量为5g/L，PAC的投加量为6g/L，投加有机化膨润土后搅拌时间为30 min，在此条件下，废水的色度去除率可达到51.3%，处理成本为12.85元/t。O3氧化法的最佳条件为：废水的pH保持不变，O3流量为5g/h，反应时间为2 min，在此条件下，废水的色度去除率可达到68.8%，处理成本为0.96元/t。对比这两种方法，O3氧化法处理该废水成本更低、效率更高，并且能提高废水的可生化性以便后续处理。 关键词：维生素B12；脱色；改性膨润土；O3氧化 中图分类号：X703.1 Studies on decoloration treatment of wastewater containing vitamin B12 by Modified mineral adsorption and O3 oxidation Abstract: Wastewater containing vitamin B12 which came from a pharmaceutical factory was treated by methods of Modified mineral adsorption and O3 oxidation. In order to get over 50% colority removal rate, the optimum operating conditions of two methods were carried out by experiments. The results were shown that the optimal conditions of modified mineral adsorption treatment were as follows: pH value of the wastewater was 3.00, dosage of organo-bentonite was 5g/L, dosage of PAC was 6g/L, mixing time was 30 minutes, under those conditions, the removal rate of colority was 51.3% and the treatment cost was 12.85 yuan per ton; the optimal conditions of O3 oxidation treatment were as follows: pH value of the wastewater was 2.70, the flow of O3 was 5g/h, the reaction time was 2 min, under those conditions, the removal rate of colority was 68.8% and and the treatment cost was 0.96 yuan per ton. Comparing the two methods, O3 oxidation treatment is cheaper, more efficient and can improve the biodegradability of wastewater. Key words：vitamin B12; decoloration; modified bentonite; O3 oxidation 作者简介邢奕(1976-)教授主要从事污水处理与回用剩余污泥资源化处理、工业烟气治理方面的科研E-mail: xingyi@ustb.edu.cn 制药废水具有有机物含量高、成分复杂、水质水量变化大、毒性强、可生化性差等特点，属高浓度难降解有机废水[1]，特别是高色度的制药废水，如不能有效处理会对生态环境造成严重后果[2]。目前，常见的废水脱色方法有吸附法、混凝法、氧化还原法、生物法、膜法等。如何简单、经济、有效地对制药废水进行脱色处理是当今的一个难题。 改性矿物吸附法主要利用改性后的矿物膨润土吸附废水中的显色物质。膨润土的主要成分是具有很强吸附能力[3]的蒙脱石，改性后的膨润土具有更强的吸附能力[4-