环境科学研究文稿审阅处理表.docVIP

重金属离子对不同非水溶性有机物含量土壤胶体上十溴联苯醚迁移行为的影响1* 1. 苏州市职业大学，环境与检测研究室，江苏 苏州 215104 摘要：为了研究复杂土壤环境中非水溶性有机物和重金属离子对BDE-209溴联苯醚时空迁移过程和变换规律在旋转混匀仪(30±1.0) r/min、温度为(25.0±0.5)℃〕内避光试验条件下水土比5、pH6.8±0.1条件下森林和农田非水溶性有机物含量和重金属离子Fe3+、Cu2+、Zn2+含量对土壤中BDE-209十溴联苯醚环境迁移行为的影响. 结果表明重金属离子在森林土和农田土壤胶体上平衡时间平衡含量分别为40 h32 h和(49.4±1.2) mg/g、(81.7±1.9) mg/g. 重金属离子对金属负荷≤60 mg/g金属负荷≤80 mg/g土壤胶体混凝沉降强弱作用均依次为Fe3+Cu2+、Zn2+，而金属负荷60~100 mg/g、农田土重金属负荷80~100 mg/g时，森林土和农田土壤胶体浓度分别稳定在(49.3±1.3) mg/L和(50.4±1.1) mg/L致使上清液BDE-209浓度由(388.5±13.2) ng/L分别降至(24.7±21.7) ng/L(25.4±18.8) ng/L. 此外金属离子未实现BDE-209由土壤胶体向金属胶体的再分配过程上清液中BDE-209浓度与土壤胶体浓度比值保持在493.1±6.8) ng/g〕，仅通过改变土壤胶体环境行为来影响BDE-209迁移过程进而导致BDE-209时空迁移过程与土壤胶运移行为. 关键词：土壤胶体非水溶性有机物重金属离子BDE-209(十溴联苯醚 中图分类号：X131.3 Effects of Heavy Metal Ions on Transports of deca-Brominated Diphenyl Ether by Soil Colloids with Insoluble Organic Matters 1 1. Lab of Environment and Analysis, Suzhou Vocational University, Suzhou 215104, China Abstract：To illustrate the transport behaviors of deca-brominated diphenyl ether (BDE-209) in soils with the different contents of insoluble organic matters, the heavy metal ions of Fe3+, Cu2+ and Zn2+ with the loads of 0-100 mg/g were involved. The verities of the forest soil colloids (≤ 1 μm, insoluble organic matters of 2.2%) and the farmland soil colloids (≤ 1 μm, insoluble organic matters ———————————— 收稿日期： 修订日期： 基金项目：江苏省高等学校大学生创新创业训练计划项目(201411054003Y)；苏州市科技局〔产业前瞻性应用研究(工业)指导性计划〕；苏州市职业大学校级课题(SVU2015YY02) 作者简介：*责任作者 of 4.7%) with BDE-209 were carried out to check their transport behaviors with the rotary mixers under the conditions of r = (30.0 ± 1.0) r/min, T = (25.0 ± 1.0)℃, the ratio value of water and soil = 5 and pH = 6.8 ± 0.1. It was concluded that the balance times and the equilibrium contents of the heavy metal ions (Fe3+, Cu2+ and Zn2+) were 40 h and (49.4 ± 1.2) mg/g for the forest soil colloids and 32 h and (81.7 ± 1.9) mg/g for the farmland soil colloids, respectively. For both for the forest soil colloids (loads of 0-60 mg/g) a