HBL101从镍钼矿焙烧料高酸浸出液中直接萃取钼的研究分析.docVIP

HBL101从镍钼矿焙烧料高酸浸出液中直接萃取钼的研究 廖小丽，肖连生，孙亚辉，曾理 （中南大学 冶金与环境学院，长沙 410083） 摘要：采用新型萃取剂HBL101从镍钼矿焙烧料高酸浸出液中直接萃取钼。考察有机相组成、料液酸度、相比、振荡频率、平衡时间、温度对钼萃取过程的影响，并绘制了HBL101萃钼等温曲线。在优化的工艺条件下，钼萃取率达96.8%以上，有机相饱和容量为12.09 g/L；负载有机相用纯水洗涤后经3级逆流氨水反萃，钼反萃率达99.9%以上，实现了钼镍分离及钼的富集转型。 关键词：HBL101；镍钼矿；萃取；分离Study on Molybdenum Extraction with HBL101 from High Acid Leaching Solution of Ni-Mo Ore after Roasting LIAO Xiao-li, XIAO Lian-sheng, SUN Ya-hui, ZENG Li (School of Metallurgy and Environment, Central South University, Changsha 410083, China) Abstract: A novel extractant of HBL101 was used to extract molybdenum directly from a strong acid leaching solution of Ni-Mo ore after roasting. The effects of organic phase composition, acidity of feed solution, phase ratio, oscillation frequency, equilibrium time and temperature on molybdenum extraction were investigated. The extraction isotherm of molybdenum with HBL101 was drawn. The results show that molybdenum extraction rate can reach 96.8% above and saturation capacity of organic phase is 12.09 g/L under the optimum conditions. The molybdenum back extraction rate is 99.9% above after the loaded organic phase is washed by pure water and three-stage of counter-current stripped by ammonia. Separation of molybdenum and nickel, as well as enrichment and transformation of molybdenum are finally achieved. Key words：HBL101Ni-Mo ore; extraction; back extraction; separation 镍钼矿为我国特有的一种多金属复杂矿资源，分布广、储量大、有价金属镍钼品位高，还含有丰富的铂族金属及稀土金属[1-3]。从镍钼矿中提取有价金属钼和镍的研究[4-10]，开发了氧化焙烧碱浸提钼和酸性氧化浸出直接提取镍钼的工艺。采用酸性氧化浸出工艺，钼浸出率达到99%以上，镍浸出率也高达90%，同时杂质铁、钙、镁、磷、砷、硅等一并进入浸出液，目前从酸浸液中回收钼的方法主要有化学沉淀法、离子交换法和溶剂萃取法。化学沉淀法需要加碱中和，所得产品是钼磷砷的混合物且钙含量较高，产品经济价位较低；离子交换法一般也需将浸出液加碱调pH至3~4后才能进行，过程中消耗大量的碱，且钼与磷、砷、硅等杂质不能分离；溶剂萃取法在从酸性溶液中提取钼的过程中占据重要地位，但至今还没有采用萃取法从含酸量高达1~6 mol/L的酸浸液中回收钼的报道。虽然有报导采用N235从酸性溶液中萃取分离镍钼且效果良好[11-12]，但要求料液pH为2~3左右，且钼与磷、硅、砷等杂质的分离效果不佳。本文采用一种新型萃取剂HBL101对从镍钼矿高酸浸出液中直接萃钼分离镍和磷、砷、硅等杂质进行系统研究。 1 试验部分 1.1 原料试剂及设备镍钼矿酸浸液H+浓度4 mol/L左右，主要成分g/L）：Mo 12.800、Ni 4.840、Fe 14.050、Ca 0.547、Mg 2.274、Al 3.567、Cu 0.365、Zn 0.579