孔祥明-吸附水-适应性201009.pdfVIP

基于自由溶液量的水泥 减水剂系统相容性研究- 韩松，阎培渝，孔祥明 (清华大学 土木工程系 土木工程安全与耐久教育部重点实验室，北京 100084) 摘 要：通过改变水灰比、减水剂掺量，测定不同时间水泥浆体中的自由溶液量、浆体流动度与流动度经时损失，并利用光学显微镜直接观测新拌 水泥浆体中水的分布情况以及水泥颗粒的絮凝情况，研究自由溶液量的变化情况及其对浆体流动度和泌水的影响规律。研究结果表明，吸附水对水 泥-减水剂系统的初始流动度、流动度经时损失和泌水等相容性表现有重要影响。增加水泥浆体中的吸附水，能够改善水泥-减水剂系统的相容性。 掺加减水剂，在打破絮凝结构的同时增加吸附水，从而提高浆体的流动性。聚羧酸减水剂增加吸附水的能力要高于萘系减水剂。过掺减水剂不是导 致泌水的主要原因，过大的水灰比和水泥颗粒表面吸附水的能力不足才是导致泌水的根本原因。 关键词：减水剂；相容性；自由溶液量；吸附水；泌水 中图分类号: TU528.042.2 文献标示码: A 文章编号: ????-????(2010) STUDY ON THE COMPATIBILITY OF CEMENT-SUPERPLASTICIZER SYSTEM BASED ON THE AMOUNT OF FREE SOLUTION HAN Song ，YAN Peiyu，KONG Xiangming (Key Laboratory of Civil Engineering Safety and Durability of China Education Ministry, Department of Civil Engineering, Tsinghua University, Beijing 100084, China) Abstract: The changes of free solution amount, fluidity and the time-depended fluidity loss of cement paste were examined by varying the water-cement ratio and the dosages of superplasticizer. The distribution of solution and flocculation microstructure in fresh cement paste was observed with optical microscope. The change of free solution amount and its effect on the fluidity and bleeding of cement paste was studied. The results show that the adsorbed solution amount has great influence on the compatibility of cement-superpasticizer system, including the bleeding degree, the fluidity and its time-depended fluidity loss of cement paste. Superplasticizer increases the fluidity of cement paste by destroying the flocculated cement particle structure and increasing the amount of adsorbed solution. Polycarboxylate superplasticizer shows higher ability of adsorbtion than naphthalene superplastcizer. Over dosage of superplasticizer is not the primary cause of bleeding. The principl