酚醛树脂炭含量对炭纸组织结构和性能的影响.pdfVIP

2011年第 1期 CARBONTECHNIQUES 2Ol1№ 1 第 30卷 炭 素 技 术 VO1．30 酚醛树脂炭含量对炭纸组织结构和性能的影响 金谷音，谢志勇，黄启忠 (中南大学 粉末冶金国家重点实验室，湖南 长沙 410083) 摘 要：对预制PAN基炭纤维纸进行树脂浸渍、模压和高温热处理，制备燃料电池用炭纸。借助SEM和XRD等技术研究了炭 纸的微观结构和石墨化度。分别用压差法、四探针电阻法和拉伸测试测得炭纸的透气率 、面电阻率和拉伸强度。结果表明：增加 PF树脂炭含量可以提高炭纸的体积密度和拉伸强度，但导致透气性能下降。树脂炭含量的增加也有助于炭纸形成发达的三维 网络状结构，炭纸的导电性能得到改善，炭纸整体石墨化趋势有一定的加强。当PF树脂炭含量为54％时，炭纸透气率为 2050 mL·mm／(cm ·h，mmAq)，密度为0．48g／cm3，面电阻率21．1mQ ·cm，石墨化度 58％，抗拉强度达到 15MPa，基本满足炭 纸的应用要求。 关键词：质子交换膜燃料电池；炭纸；透气率；石墨化度；面电阻率；拉伸强度 中图分类号：TB332；TM911．4 文献标识码 ：A 文章编号：1001．3741(2011)0l一19．O5 EfflectsofPF resin char content0n structureand properties0fcarbon paper JINGu·y·in,XIEZhi-y·ong,HUANGQi—z·hong (StateKeyLaboratoryofPowderMetallurgy，CentralSouthUniversity,HunanChangsha410083，China) Abstract：Carbonpaperforpreparingprotonexchangemembmnefuelcell (PEMFC)wasmadebyimpregnatingPAN—based carbon fiber prefab compactwith PF resin， moulding and high temperature heattreatment． Microstructure characteristics and degree ofgraphitization ofcarbon paper were analyzed by SEM and XRD． Gaspermeability，electricalproperty and tensile strengthofthethecarbon paperproductsobtainedweDgmeasuredby thedifferentialpressuremethod，thefour—probetechnique and tensile test， respectively．The resultsindicate thatwith the increase ofPF resin charcontentin the carbon paper， gas permeability decreased whereasbulk density and tensilestrength increased．The increase ofPF resin charcontentalsoenhanced thefomr ationofthethreedimensionalconductivenetwork in ca~on paperthusimproved both theoverallgraphitization tendency ofcarbon paperand itselectrical property．When thePF resin charcontentwas54％，thepropertiesofcrabonpaperwereas follows：gaspemreabilitywas2050mL ‘mm／(cm ·h。mmAq)，bulkdensit