本实验CO 2 的吸收属于液膜控制过程.PPT

气液传质系数的测定方法 1.水吸收CO2的液相总传质系数测定 长安大学，李文新，2004 理论基础 2.圆盘塔中CO2吸收的液膜传质系数测定 The EndThank You Logo * Logo Diagram 2 Diagram 2 根据传质速率方程，得微分方程： 联立求积分： 本实验CO2的吸收属于液膜控制过程，则Kl=kl，kla即为液相总传质系数。 实验装置 通过线性回归的最小二乘法，得到二氧化碳气体吸收的液相总传质系数的准数关联式： 华东理工 实验原理 CO2在塔中与吸收液逆流接触，之后从塔顶出来经压力计至皂膜流量计排空。 3.Diffusion of Methane, Ethane, Propane, and n-Butane in Water P. A. Witherspoon and D. N. Sarat, University of California, Berkeley Diffusion coefficients for methane, ethane, propane, and n-butane in water were measured at temperatures ranging from 24.8° to 42.6° using the capillary-cell method. Experimental Section We used a specially designed capillary of variable length having an internal diameter of about 0.1 cm. By filling a known length of the capillary with an aqueous solution of a given hydrocarbon, the system is then ready for immersion in a constant-temperature bath. The aqueous solutions were prepared by bubbling the hydrocarbon gas through distilled water for about 0.5 hr. and allowing the solutions to equilibrate for 1 or more days in a constant-temperature air bath. After an appropriate diffusion time had elapsed, the hydrocarbon concentrations remaining in the capillary were measured in a gas chromatograph equipped with a hydrogen-flame ionization detector. D may be calculated from when the value of the parameter Dt/L2 is greater than 0.23， 1 reduces to Logo