三氯化铁催化合成丁醛1,2丙二醇缩醛.pdf

RARE METALS, Vol. 27, No. 1, Feb 2008, p. 89 Catalytic synthesis of acetals and ketals with H PW O /PAn 3 12 40 a, b a a b YANG Shuijin , ZHANG Yijun , DU Xinxian , and Philippe G. Merle a Hubei Key Laboratory of Bioanalytical Technique, Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China b Department of Chemistry and Biochemistry, Concordia University, Montreal H4B 1R6, Canada Received 28 September 2006; received in revised form 21 November 2006; accepted 28 November 2006 Abstract A new environmental friendly catalyst H3PW12O40/PAn was prepared and identified by means of FT-IR, XRD, and TG/DTA. The optimum conditions have been found; that is, the mass ratio of PAn to H PW O is 1:1.5, the volume of methanol is 20 mL, and the reflux reaction 3 12 40 time is 3 h. The structural identity of Keggin units is preserved after the incorporation into polyaniline matrix. Catalytic activities of H PW O /PAn in synthesizing 2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane,2,4-dimethyl-2-ethoxycarbonylmethyl-1,3-dioxolane, cy- 3 12 40 clohexanone ethylene ketal, cyclohexanone 1,2-propanediol ketal, butanone ethylene ketal, butanone 1,2-propanediol ketal, 2-phenyl-1,3-di- oxolane, 4-methyl-2-phenyl-1,3-dioxolane, 2-propyl-1,3-dioxolane, and 4-methyl-2-propyl-1,3-dioxolane were reported. It has been demon- strated that H3PW12O40/PAn is an excellent catalyst. Various factors concerned in these reactions were investigated. The