净水活性炭吸附偶氮胂光度法监测废水中铀.pdfVIP

37 6 - Vol. 37 No.6 2001 6 PTCA ( PA T B: CHEMICAL ANALYSIS) June 2001 ( , 410011) : 研究了净水用活性炭吸附铀矿坑道水和重铀酸铵沉淀母液中铀试验表明, 控制流 相的pH 值为4.7~ 8. 0, 逆流通过40cm 高的活性炭层, U( ) 的吸附率 96% 用高灵敏度的 U( )-偶氮胂光度法, 可以快速地监测废水和排放水中铀的浓度 : 光度分析; 活性炭; 废水; 铀; 偶氮胂 : O659.321 : A : 1001-4020(2001)06-0261-02 PHOT OMET IC MONIT O ING OF U ANIUM IN WASTE WATE AFTE ITS SEPA ATION BY ADSO PTION ON ACTIVE CA BON TANG Guo-liang ( Central-south Geolog ical B ureau of N uclear I nd ustr y , Changsha 410011, Ch ina) Abstract : A study on the separation of uranium in the uranium mine gallery water and in the mother liquor of pre- cipitation of ammonium uranate by adsorption on active carbon is reported in this paper. It is found that a recovery of greater than 96% is obtained by this adsorption process, when thewastewater at pH 4. 7~ 8.0 is acted as mobile phase and is passed through a column packed with a layer of active carbon of 40cm in height in a counter current direction. The uranium remained in the effluent wast water from the adsorption column is then determined photometrically with arsenazo as chromogenic reagent. The hexavalent uranium is reduced rapidly by the new reduction system composing of Fe ( ) , EDTA and ascorbic acid. Keywords: Photometry; Active carbon adsorption; Uranium; Waste water; Arsenazo , - 1 5 () ,mgL , ( = 1.02 10 ) 660nm - 1 [1] [4] [(U) 50gL ] , U( )- , , Fe(