氢渗透通过金属膜引起的塑性形变.pdfVIP

d p d G Vol No d ACTA METALLURGICA SINICA Mar pp
zrxj  f      IwsswhNVsasb  MztYltbZ SZaZSSjZPiaAy YlleoSlFSlXJSl ElMSbtlFDSAJAbDSlnSSMD SSQbu mpi SwdZl  klto TG O   gv A   eo PLASTIC DEFORMATION OF METALLIC MEMBRANE INDUCED BY HYDROGEN PERMEATION HOU Minqiang ZHANG Wushou Key Lab oratory of Colloid Interface and Chemical Thermo dynamics Institute of Chemistry Chinese Academy of Sci ences Beijing Correspondent HOU Minqiang lectuer Tel Email houmqiccasaccn Supported by National Natural Science Foundation of China Nos CCD of and and Specialized Pr ophasic Basic R esearch Pr oject No the Ministry of Science and Technology of China Manuscript received in revised form ABSTRACT A mo del for hydrogen diusion across a metallic tub e typ e membrane is established This mo del is a combination of the shell mechanics elastoplastic mechanics theories of thermostresses and metalhydrogen interactions Elastic plastic and residual stresses and their eects on hydrogen distribution and transp ortation and material prop erties are discussed It is found that the hydro gen diusion slows down in the plastic region and lo cal thermo dynamic prop erties of metalhydrogen systems are mo died The plastic stress can b e avoided by using small charging current during hy drogen charging pro cesses This result can b e used for applications of hydrogen purication isotopic separation storage and transp ortation KEY W ORDS hydrogen p ermeation membrane palladium alloy selfstress plasti