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Front. Environ. Sci. Engin. China 2009, 3(2): 171– 177
DOI 10.1007/s11783-009-0017-4
RESEARCH ARTICLE
Selective sorption of perfluorooctane sulfonate on
molecularly imprinted polymer adsorbents
Shubo DENG, Danmeng SHUAI, Qiang YU, Jun HUANG, Gang YU (✉)
Department of Environmental Science and Engineering, POPs Research Center, and State Key Joint Laboratory of Environment Simulation and
Pollution Control, Tsinghua University, Beijing 100084, China
© Higher Education Press and Springer-Verlag 2009
Abstract Perfluorooctane sulfonate (PFOS), as a poten- 1 Introduction
tial persistent organic pollutant, has been widely detected
in water environments, and has become a great concern in Perfluorochemicals have been used in many products for
recent years. PFOS is very stable and difficult to about 50 years. They are commonly used as surfactants for
decompose using conventional techniques. Sorption may metal plating, fire-fighting foams, varnishes, vinyl poly-
be an attractive method to remove it from water. In this merization, gasoline, and water repellents for leather,
study, the molecularly imprinted polymer (MIP) adsor- paper, and textiles [1–3]. Perfluorooctane sulfonate
bents were prepared through the polymerization of 4- (PFOS) is of increasing scientific and regulatory interest
vinylpyridine under different preparation conditions in because it is the end product of the degradation of most
order to remove perfluorooctane sulfonate (PFOS) from perfluorochemicals and has been detected in wastewater,
water. The MIP adsorbents using perfluorooctanoic acid surface water, sediment, and many wildlife species [4–6].
(PFOA) as the template had good imprint
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