有机难溶盐膜抑制黄铁矿氧化的研究 - 环境科学学报.PDF

19 4 Vol. 19, o. 4 1999 7 ACTA SCIE TIAE CIRCUMSTA TIAE July, 1999 兰叶青 ( , 210095) 黄 骁 胡霭堂 ( ) 25 pH 35 7 , ( FeS ) 01mol L- 1 H O + 005% , 2 2 2 , . 400min , 9978%9954% 9950%, 9579%9745%9970% . 3 pH , 480min pH 3 01mol L- 1H O 2 2 400 min , 9492%9617%9816%9831%9884%9891% . ; ; ; . Control of pyrite oxidation by film of organi c salt 1) 2) 2) LA Yeqing , HUA G Xiao , HU Aitang ( 1) Science College of anjing Agricultural University, anjing 210095; 2)Resources and Environment Collegeof anjing Agricultural University, anjing 210095) - 1 Abstract At 25 and pH 3, 5 and 7,by leaching pyrite with the solution containing 01mol L H O 2 2 + 005% chelatingagent, a black film of chelating iron forms on the surface of pyrite,which can control the oxidation of pyrite effectively.The percentages of remnant pyrite leached by the solution for 400 min were 9978%, 9954% and 9950%, of the three pHs respectively, as the controls were 9579%, 9745% and 9970%. When the samples of pyrite treated with the solution containing 01mol L- 1 - 1 H O + 005% chelatingagent at the three pHsfor 480min were leachedagain with 01mol L H O at 2 2 2 2 pH 3 for 400 min, the remains of treated pyrite were increased from 9492% to 9831%, 9617% to 9884% and 9816% to 9891% by comparing with the controls. Keywords pyrite, acid mine drainage, film of organic salt, oxidation. 1 , . ,, , (acid mine drainage, AMD)