高纯偏钒酸铵的制备技术研究 - 钢铁钒钛.pdfVIP

第34卷第3期 钢摇 铁摇 钒摇 钛 Vol.34,No.3 2013年6月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 June2013 高纯偏钒酸铵的制备技术研究 侯海军 (攀钢集团钒业有限公司,四川 攀枝花617023) 摘摇 要:从生产流程、工艺过程控制参数选取等方面分析了偏钒酸铵产品中杂质含量偏高的原因。 研究了APV在 不同温度条件下,过滤杂质含量的变化趋势,除杂系数的调整,碱性沉钒铵盐的选择以及沉淀加铵系数等重要参数 对杂质含量控制的影响。 通过先运用低铵盐沉钒制取多钒酸铵、再返溶除杂净化、最后碱沉的工艺流程,有效地将 Cr、Si、Al等主要杂质含量由原来的0.05%以上降低至目前的0.02%以下,对攀钢现有高纯钒生产技术的提高具有 重要的指导意义,为攀钢钒业新产品的开发奠定了基础。 关键词:偏钒酸铵;沉钒;多钒酸铵;高纯钒;返溶 中图分类号:TF841郾3摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)03-0029-04 DOI:10.7513/ j.issn.1004-7638郾2013郾03郾006 Preparation Technique of High Quanity Ammonium Metavanadate Hou Haijun (Vanadium Industry Co. ,Ltd. ,Pangang group ,Panzhihua617023,Sichuan,China) Abstract:This paper analyzed the cause of high impurities in ammonium metavanadate products at the aspect of theproductionprocessand selectionof processcontrolparameters. To controlthecontent of im鄄 purities in AMV,the change trend of the impurity content after filtering,adjustment of the impurity re鄄 moval coefficient and the selection of ammonium salt in basic precipitation were investigated in different temperature conditions. Inthetechnological processof preparing ammoniumpolyvanadate (APV)by low ammonium salt precipitation,return dissolving the APV to remove the impurity,and then precipitating AMV in basic condition,the impurities in AMV could be reduced from 0.05% to 0.02% effectively, which was of important guiding significance onthe improvement of high purity vanadiumproductiontech鄄 nology,andlaidafoundationtodevelopnewproductsforVanadiumindustry Co. ,Ltd. ,Panganggroup. Key words:ammonium metavanadate,precipitation of vanadium,ammonium polyvandata,high purity va鄄 nadium,backwa