导电聚氨酯分散体的制备及应用.pdfVIP

2010 38 4 77 , (华南理工大学化学与化工学院, 广东 广州 510640) :(MPEG), ( PNA)( IPDI), (PUD), PUD PEDOT, IR TEM , , PU , PEDOT, , PET :; ; PEDOT; P reparation and App lication of Conducting Polyurethan e D ispersion ZHANG Sha, S UN D ong - cheng ( Schoolof Che istry and Che icalEngineering, South ChinaUniversity ofTechnology, Guangdong Guangzhou 510640, China) Abs tract: Polyurethanedispersion(PUD) was synthesized by using poly ethyleneglycol ono ethylether(MPEG), poly adipate neopentyl glycol ester(PNA) and isophorone diisocyanate( IPDI) with the acetone ethod. Conducting polyurethane dispersion was prepared by PEDOT oxidative poly erization in PUD, using a oniu persulfate as oxidant, and characterized by IR, dyna ic light scattering and TEM. Results showed that the conductive polyurethane co posites ca e intobeing core- shellstructurewith PU latex core andPEDOT shell. Theprocedure forgenerating core- shellco positeswasdiscussed. Antistatic coatingwasprepared by using the conducting polyurethane dispersion and successfully applied on plastic substrate ofPET. K ey w ord s: polyurethane dispersion; conducting poly er; PEDOT; antistatic coating , (MPEG),M = 2000, Clariant, ; n , ( IPDI), 3, 4- ( EDOT ), Bayer, [ 1- 3] ; (TMP),; , ; ( SDBS), , ; ( ( NH ) S O , APS), 4 2 2 8 ,, ; , ( Tensor 27, Brucker [ 3] ,, ); ( ZetaPlus DB - , [4- 6] [ 7] 525, Brookhaven); TEM ( Tec