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Article pubs.acs.org/IECR The Impact of Metal Oxides on the Combustion Behavior of Ethylene−Vinyl Acetate Coploymers Containing an Intumenscent Flame Retardant Lei Wang,†,‡,§ Wei Yang,†,‡,§ Bibo Wang,† Yu Wu,† Yuan Hu,†,§, * Lei Song,†, * and Richard K. K. Yuen‡ †State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, Peoples Republic of China ‡Department of Building and Construction, City University of Hong Kong and USTC-CityU Joint Advanced Research Centre, Suzhou, Peoples Republic of China §Suzhou Key Laboratory of Urban Public Safety, Suzhou Institute of University of Science and Technology of China, Suzhou, Peoples Republic of China ABSTRACT: The objective of this work was to compare the flame retardancy of intumescent flame retardant ethylene−vinyl acetate (EVA/IFR) composites containing different metal oxides including lanthanide oxide, iron oxide, the mixture of iron oxide and lanthanide oxide, and lanthanum ferrite nanocrystalline (LaFeO3). A novel compound containing iron and lanthanum, LaFeO3 was successfully prepared. The EVA/IFR composites with these different coadditives were then fabricated through a melt blending process. Thermogravimetric analysis data showed that these different coadditives could increase the char residue formation. Cone calorimeter results revealed that these different coadditives and IFR could clearly change the decomposition behavior of EVA and form a char layer on the surface of the composites, consequently resulting in efficient reduction of the flammability parameters, such as heat release rate, total heat release, ave