金属有机骨架的合成和应用.pdfVIP

化 学 与 黏 合 2009 年第31 卷第3 期 CHEMISTRY AND ADHESION ·61 · 金属有机骨架的合成及应用 * 尹作娟，高 翔，孙兆林， 宋丽娟 ， 张晓彤 （辽宁石油化工大学辽宁省石油化工重点实验室，辽宁抚顺113001） 摘要：金属有机骨架（Metal- organic Frameworks,MOFs）材料是目前受到广泛关注的一种新功能材料，具有特殊的拓扑结 构、内部排列的规则性以及特定尺寸和形状的孔道，而且制备MOFs 的金属离子和有机配体的选择范围非常大，经常具有不饱 和配位的金属位和大的比表面积，这在化学工业中有着广阔的应用前景。以设计与合成MOFs 所用的配体类型为线索，着重对 MOFs 的合成和发展现状进行了综述；总结了金属有机骨架材料在催化剂、气体的储存和分离方面的应用，并对这种新型多功 能材料在设计、合成与应用中的广阔前景做了展望。 关键词：金属有机骨架；配位聚合物；多孔材料；催化剂；气体储存 中图分类号：TQ 426.61 文献标识码：A 文章编号：1001- 0017（2009）03- 0061- 05 Synthesis and Applications of Metal-organic Frameworks YIN Zuo-juan, GAO Xiang, SUN Zhao-lin, SONG Li-juan and ZHANG Xiao-tong （Liaoning Key Laboratory of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China） Abstract: MOFs are concerned especially at present which are new functional materials, they have special topological structure, regularity of internal arrangement and pore canal with specific size and shape. Moreover the choice of metallic ion and the organic ligand which is used to preparing MOFs is very wide. MOFs usually have unsaturated-coordinate metal site and large specific surface area, so they have a broad application prospect in the chemical industry. The synthesis and current progress in MOFs were reviewed according to the ligands types which were used to prepare MOFs. And the applications of MOFs in the fields of catalyst, gas storage and separation are summarized. In addition, several trends of designing MOFs as functional materials are also presented. Key words: