天然药化保研试题.docVIP

一、天然药化的英语翻译：是关于一种化合物结构鉴定和提取分离的文章，准确翻译每一句话不容易，但也不要想得太难。多看天然药化方面的文献，会很有帮助。我觉得翻译量不大，但准确翻译“结构鉴定”部分的话比较费事。我举个例子，当时考的不是这个化合物。???Structure?Elucidation：（阐述）?????????Compound?1?was?obtained?as?a?colorless?powder,?Its?UV(MeOH,????max,?nm,?log????)?showed?the?absorptions燼t?03?4.2),255?3.9).燭he燞R-ESI-MS爏pectrum爏howed燼quasi-molecular爄on爌eak燼t爉/z?89.136?燵M?燦a]+,爄ndicatingthat爄ts爉olecular爁ormula爓as燙22H22O5?calcd爁orC22H22O5Na,爉/z?89.1359).燭he營R爏pectrum爀xhibited燼bsorption燽ands爋f燾arbonyl爂roup燼t??59燾m1燼nd燼romatic爂roup燼t??01燾m??07燾m1.營n?H燦MR?500燤Hz,CDCl3)爏pectrum,爋ne爏eries爋rtho燾oupled燿oublets（邻位耦双峰）?at?7.04(4H,?d,?J?=?8.7?Hz)?and?7.40?(4H,?d,?J?=?8.4?Hz)?showed?the?presence?of?two?para-substituted（对位取代）?benzene?rings.?The?signals?at?6.62?(2H,?d,?J?=?15.9?Hz)?and??6.27?(2H,?td,?J?=?6.0,?15.9Hz)?could?be?assigned?to?two?pairs?of?olefinic?protons（烯键质子）,?of?which?the?downfield?chemical?shift?confirmed?that?they ?were?linked?to?the?aromatic?ring.?The?protons?at?4.20?(4H,?dd,?J?=1.5,?6.0?Hz)?suggested?that?there?were?two?methylene?（亚甲基）groups?attached?to?the?olefinic?groups,?and?its?downfield?chemical?shift?revealed?that?the?methylene?groups?might?have?oxygen?atoms?on?the?other?side.??????Experimental:The?rhizomes（根茎）?(20?kg)?were?cut?into?pieces,?refluxed?with?95%?EtOH,?then?concentrated?in?vacuo.?The?solution?continued?to?be?concentrated?to?afford?a?residue（残渣）,?which?was?partitioned?between?H2O?and?petroleum?ether,?CHCl3,?successively.The?CHCl3?fraction?(237?g)?was?subjected?to?silica?gelcolumn?chromatography,?being?eluted?with?CHCl3-MeOH(99?:?1?5?:?5).?The?fraction?of?99:1?eluate?was?chromatographed?on?silica?gel?column?and?then?purified?by?Sephadex?LH-20?column?chromatography?to?afford?1?(3?mg). 1天然药化 1水解所需试剂、玻璃仪器 2 画出装置图 3怎样处理反应液，可以作为TLC的实验溶液？苷元和单糖的展开系统应该是？