Biodiesel from rapeseed oil of turkish origin as an alternative fuel：（菜籽油生物柴油的土耳其裔作为替代燃料）.pdfVIP

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Biodiesel from rapeseed oil of turkish origin as an alternative fuel：（菜籽油生物柴油的土耳其裔作为替代燃料）.pdf

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9 1997by Hurnana Press Inc. All rights of any nature whatsoever reserved. 0273-2289/96/6103--0251508.75 Biodiesei from Rapeseed Oil of Turkish Origin as an Alternative Fuel F. KARAOSMANOGLU,*A. AKDAG,AND K. B. CIGIZOGLU lstanbul Technical University, Department of Chemical Engineering, 80626 Maslak, lstanbul, Turkey Received August 25, 1995; Accepted October 20, 1995 ABSTRACT The crude rapeseed oil was transesterified using methanol and using sodium hydroxide as a catalyst, and the varieties affecting the monoester yield were investigated. The methyl ester fuel called Bio- diesel, produced under the determined optimum reaction conditions, was tested according to the standard methods for its fuel properties. Biodiesel fuel properties were found to be very close to those of Grade No. 2-D diesel fuel. Index Entries: Rapeseed oil;BrassicanapusL.; transesterification; methyl ester; alternative diesel fuel; biodiesel; biofuel; C1engine fuel. INTRODUCTION Vegetable oils are the most important biomass origin for alternative motor fuels. The use of vegetable oils as source of energy has long been known. History records that the first studies concerning the use of vegetable oil started in the year 1928 and that R. Diesel, the inventor of the engine that bears his name, used vegetable oils as a fuel in his engines (1,2). For many years, the ready availability of inexpensive petroleum middle distillate fuels provided little incentive for experimenting with alternative, renewable fuels for diesel engine. The energy crisis of the 1970s sparked a renewed interest in the use of vegetable oils as fuels and today the subject continues to attract attention because of