细乳液界面聚合模板法制备双壁相变材料纳米胶囊 张学静.pdfVIP

39 1 　　　　　 V ol.39 N o.1 2011 1 N EW CH EM ICA L M A T ERIA LS ·4 5 · 张学静　王建平　张兴祥＊ (天津工业大学功能纤维研究所,改性与功能纤维天津市重点实验室, 天津300 160 ) 　　通过 乳液界面聚合法制备出了以正十八烷为囊芯, 聚脲为壁材的纳胶囊, 再以此聚脲壁材为模板, 使苯乙 烯与交联剂二乙烯基苯在内表面共聚形成双层壁材相变材料纳胶囊。采用扫描电子显微镜, 差示扫描量热仪, 热重分析 仪, 粒度分析, 红外光谱等手段分别考察了纳胶囊的表面形态、相变性能、热稳定性能、粒径分布及胶囊结构等。 实验结果 表明,超声乳化5m n,所得纳胶囊粒径分布均匀, 平均粒径在 0.4 1μm, 无过冷现象, 囊芯含量高达 50%, 耐热温度达 206 ℃。 　双壁纳胶囊, 乳液聚合, 正十八烷, 聚脲,聚苯乙烯 Preparation of double-shell nanoencapsulated phase change materials by interfacial polymerization in an emulsion system Zhang X uej ng 　Wang J anp ng 　Z hang X ng x ang (T anj n M un c pal Key Lab o f F be r Mo d f cat o n and Funct onal F bers, Inst tute of F unct onal F bers, T anj n Poly techn c Un vers t y, T anj n 300160) Abstract 　T he nanoencap sulated phase change mater als (N anoPCM s)w th po ly urea/cro ssl nked polysty rene a s do uble-shell have been prepared.In the f rst step, nano encap sulated n-octadecane w a s prepared u s ng po ly urea as shell by nterf ac al m n emuls o n po ly mer zat o n.I n the seco nd step, w th fo rmed polyurea lay er as a nov el template, throug h copol- y mer zat on sty rene w th d v ny l benzene n the nne r surf ace of the templa te to o bta n a do uble-shell nanocap sule.Fur ther- mo re, the surf ace mor pholog y, pha se change pro pe rt es, thermal stab l ty, d ameter d str but on and the structur e of the nannocap sules w ere nvest g ated by scann ng electro n c m cro sco py, d ff erent al scann ng calo r me try, the rmog rav metry, laser par t cle s ze analy s s and four e r transfo rm nfra red spectro sco py