一种固 液相变材料 PCM 棕榈 省略 4 丁二醇二酯的微乳液合成与表征 张丽静.pdfVIP

37 7 　　　 Vo.l37 No.7 2008 7 AppliedChemicalIndustry Ju.l2008 - (PCM): 1, 4 - 1, 2 1 1, 2 1, 2 张丽静 , 吾满江·艾力 , 孟庆勇 , 蔡国星 (1., 　 8300 11;2. , 　 100039 ) 　:/DBSA/, 1, 4 -- 1, 4- FT-IR, 1 HNMR DSC, DSC 1, 4 - 65.8 ℃, 162.4 kJ/kg :;;-; :TQ0 31.7　　　:A　　　:167 1-3206 (2008)07-0 802-03 Preparationandcharacterizationofasolid-liquidPCM: 1, 4-butanedioldi-pamlitate 1, 2 1 1, 2 1, 2 ZHANGLi-jing, WUMANJIANG·Eli, MENGQing-yong, CAIGuo-xing (1.XinjiangTechnologyInstituteofPhysicsandChemistry, ChineseAcademyofScience,sUrumqi830011, China; 2.GraduateUniversityofChineseAcademyofScience,sBeijing100039, China) Abstrac:t1, 4 -Butanedioldi-palmitat,easolid-liquidphasechangematerial(PCM), waspreparedviathe esterificationreactionofpalmiticacidwith1, 4 -butanediolinthewater/DBSA/palmiticacidmicroemu-l sionsystem.AndthenitwascharacterizedbyFT-IR, 1 HNMR spectraandDSCmeasurement.sTheDSC resultsindicatethatthephasechangeonsettemperatureandphasechangeenthalpyof1, 4 -butanedioldi- palmitatewereat65.8 ℃ and162.4 kJ/kg, respectively. Keywords:microemulsion; esterification; solid-liquidphasechange;phasechangeenthalpy 　　(PCM), , , (1, 4 - [ 1] ) ( ) (DBSA)/ 、, DBSA/, [ 2 -3] , [ 4 -6] [7 -10] 1 、 、 1, 4 -, FT-IR, HNMR DSC [ 11] [ 12-13] 、