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2005 63 Vol. 63, 2005
3 , 234238 ACTA CHIMICA SINICA No. 3, 234238
· ·
*,a a b b
(a 510632)
(b 100080)
, .
. /, ,
.
; ; ; ;
Synthesis of Ordered Macroporous Hydrogels by Chemical
Modification
RONG, Jian-Hua*,a HU, Yong-Honga MA, Jinb YANG, Zhen-Zhongb
a
( Chemistry Department, College of Life Science and Technology, Jinan University, Guangzhou 510632)
b
( State Key Laboratory of Polymer Physics Chemistry, Institute of Chemistry, Chinese Academy of Sciences,
Beijing 100080)
Abstract Novel ordered macroporous polymeric gels were derived by chemical modification of the corre-
sponding rigid ones, which were template-synthesized by using silica colloidal crystals. In this study, sul-
fonated polystyrene ordered macroporous materials were derived from the corresponding rigid polystyrene
ones by sulfonation with concentrated sulfuric acid at high temperature. It is key that the sulfuric acid and
sulfone groups synchronously introduced are responsible for the hydrogel properties. The ordered mor-
phologies of the samples were confirmed by scanning electron microscopy observation and the replication
with titania. Meanwhile, it is demonstrated that the ordered hydrogels can be used as novel templates to pre-
pare mesostructured inorganic materials with tunable morphologies.
Keywords sulfonated polystyrene; ordered macroporous material; hydrogel; t
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