低介电损耗氟化丙烯酸聚氨酯疏水材料制备.pdf

Material Sciences 材料科学, 2011, 1, 85-92 doi:10.4236/ms.2011.13016 Published Online October 2011 (/journal/ms/) Preparation of Hydrophobic Fluoroacrylate Polyurethane Films with Low Dielectric Loss * Yudi Guo, Dongyan Tang Department of Chemistry, Harbin Institute of Technology, Harbin Email: dytang@ Received: Sep. 2nd, 2011; revised: Sep.19th, 2011; accepted: Sep. 21st, 2011. Abstract: Fluoroacrylate copolymers with different fluoroacrylate monomer content and hydroxyl monomer content are synthesized by free-radical solution polymerization. The comonomers are composed of methyl methacrylate (MMA), butyl acrylate (BA), acrylic acid (AA), 2-hydroxypropyl acrylate (2-HPA) and dode- cafluoroheptyl methacrylate (G-04). Fluoroacrylate polyurethane (FPU) is prepared by curing the copolymers with HDI (hexamethylene diisocyanate) trimer. The hydrophobicity, dielectric properties, and transparency of FPU films are investigated. The comparative investigation is carried out with polyurethane obtained by re- acting with commercial resin of ZY-1 and SGK-5701. The results indicated that fluoroacrylate polyurethane possess a lower contact angle(CA), excellent hydrophobic stability ，lower dielectric constant and dielectric loss. And the transmittance is higher in the whole visible wavelength range ( 90%) than the FPU prepared by commercial resin. The FPU film exhibits excellent hydrophobicity(CA 98˚) and hydrophobic stability with a lower water absorption ( 0.5%) by adjusting the fluoroacrylate monomer content. The dielectric con- stant and dielectric loss of the film is less than 2.5 and 0.01, respectively when the fluoroacrylate monom