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纳米al粉的热脱附研究 thermodesorption studies on al nanopowders
第13 卷 第5 期 含! 能! 材! 料 VoI. 13 ,No. 5
2005 年10 月 ENERGETIC MATERIALS October ,2005
文章编号:1006-994 1(2005 )05-0295-06
Thermodesorption Studies on Al Nanopowders
1 2 1
Oueenie S M Kwok ,Nichole Emery ,David E G Jones
(1. Canadian Exp losiues Research Laboratory ,Natural Resources Canada ;2. King s College London )
Abstract :AIuminium (AI )nanopowder has been shown to possess unigue thermaI behaviour and to enhance the per-
formance of some energetic materiaIs (EM ). However ,AI nanopowder has a high reactivity with water ,which causes
aging of AI nanopowder ,and conseguent reduction in its effectiveness in EM compositions. Water adsorption and desorp-
tion is a particuIar concern,since the aging reaction of AI nanopowders may be reIated to the water adsorbed on its surface.
The thermodesorption of adsorbed gases on nanometer-sized aIuminium powders was investigated using Thermogravimetry
(TG )and Thermogravimetry-Fourier Transform Infrared-Mass Spectrometry (TG-FTIR-MS ). The resuIts show that the AI
nanopowder studied contains 12 mass % of adsorbed gases. Desorption of water and carbon dioxide was observed by FTIR
and MS. The kinetic parameters for the desorption of the adsorbed gases were de
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