木材保护及改性7.wood-polymer composite删减部分内容.pptVIP

Lignocellulosic–plastic composites木材-塑料复合材料 Broadly meaning： ①PEG-treated wood ②Impreg ③Compreg ④ Wood-vinyl composites 习惯上把第四种称为木塑复合材，即塑合木（WPC） ;Lignocellulosic–plastic composites木材-塑料复合材料 Broadly meaning： ①PEG-treated wood ②Impreg ③Compreg ④ Wood-vinyl composites 习惯上把第四种称为木塑复合材，即塑合木（WPC） ;(1) Definition P209 Impregnating the wood with monomer, then polymerizing under γ-radiation or heat/initiator(catalyst), thus the monomer transfer into homopolymer or grafted on the wood cell wall. (2) Performances Compared with untreated wood, dimensional stability, hardness, compression strength, abrasion resistance and other strength of WPC are greatly improved, moreover, WPC have beautiful appearance and luster. 木材保护学 P209-230, wood preservation and modificationP56 (3)Application：Building materials; furniture and craftwork; cultural and gymnastic materials. 公共场所地板、木梭、线轴等、家具把手、乐器材、高尔夫球杆等。 还有哪些地方可用？;7.2.1 Materials;7.2.1.1 Suitable species;7.2.1.2 Monomers; 苯乙烯是WPC开发初期常用的单体，但由于存在聚合所需能量 大、聚合不完全等问题，现已不单独使用。;7.2.1.3 Polymerization; Dyes Crosslinking agent 常用：过氧化物交联剂 如：1,3-丁二稀，二甲基丙烯酸乙二醇酯， 三甲基丙烯酸三羟甲基丙烷等 Fire retardant ;7.2.2 Manufacturing methods;7.2.3 Differences between catalyst-heat and γ-radiation process;7.2.4 Matters needing attention;Because of the exothermic reaction temperature in the wood-monomer composite increases, and the high temperature distills the moisture out of the wood cell wall. The cell wall shrink, and the wood also shrinks and distorts. Remedial measure: machine use γ-radiation polymerization; ① Species, influence of water moisture on the polymerization exotherm. ② monomer ③ Autoacceleration ④ initiator ⑤crosslinking ⑥ additives such as Dyes,fire retardants ; The shortage of high quality hardwoods has driven researchers and wood product manufacturers to seek alternatives, lower cost resources for val