电化学氧化除氨氮过程中羟基自由基及中间产物定量分析.PDF

中国环境科学 2012,32(2) ：238~241 China Environmental Science 电化学氧化除氨氮过程中羟基自由基及中间产物定量分析 * 王春荣 ,李 炟,胡建龙,任钦毅,黄柳斌,王荣博 ( 中国矿业大学(北京)化学与环境工程学院,北京 100083) - 摘要：采用高效液相色谱对电化学氧化除氨氮过程,不同电流密度,Cl 浓度及初始 pH 值的·OH 进行定量检测和分析,同时,对不同初始 pH 值和 - 电流密度下, 电化学氧化除氨氮的中间产物进行了定量分析,结果表明:·OH 产生量与电流密度成正比,当有 Cl 存在,且在碱性条件下会抑制·OH 的产生;初始 pH 值为偏碱性时,NO2-和氯胺的产量均有所增加.建议电化学氧化脱氨氮过程,尽量保持溶液 pH 值在中性或酸性条件下;电流密度 2 时,活性物质产量最高,且有害中间产物产量最低. 对氨氮电化学氧化过程中各中间产物的量有着较大影响,在电流密度为 10mA/cm 关键词： 电化学氧化；除氨氮；羟基自由基；中间产物 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2012)01-0238-04 The quantitative analysis of hydroxyl radical produced and intermediate products in the process of electrochemical * oxidation for ammonia removal. WANG Chun-rong , LI Da, HU Jian-long, REN Qin-yi, HUANG Liu-bin, WANG Rong-bo (School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China). China Environmental Science, 2012,32(2)：238~241 Abstract ：In the process of electrochemical oxidation for ammonia removal, the concentration of hydroxyl radical (·OH) was detected and quantitatively analyzed by high performance liquid chromatography in different current density, chloride ion (Cl-)concentration and initial pH value. The concentration of ·OH produced was direct proportional to current density, and the production of ·OH would be inhibited under the conditions of existence of Cl- and alkaline. Meanwhile, the intermediates were detected and quantitatively analyzed by spectrophotometry and titration in different initial pH and