硫代乙酰胺作为标准溶液测定水中硫化物.pdfVIP

2310 2009 10 19 10 Ch inese Journal ofH ealth Laboratory T echnology, Oct 2009; Vol 19 No 10 = 硫代乙酰胺作为标准溶液测定水中硫化物 王国玲, 杨路平, 姜颖虹 (, 250014) [] : : , , : 0~ 0120 mg/L, r = 01 9996, RSD 21 42% ~ 6157% , 931 5% ~ 103% : , , , [] 硫代乙酰胺; 标准溶液; 亚甲蓝法; 硫化物 [] R 12311 [] A [ ] 1004- 8685( 2009) 10- 2310- 03 Th ioacetam ide used as standard in determ ination of dissolved su lfide in water WANG Gu o2ling, YAN G Lu2p ing, JI AN G Ying2h ong ( Shan ong Cen ter for D isease Control an Prevetion, Jinan 250014, China) [Abstract] Obj ective: Th ioacetami e was use as stan ar instea of so ium sulfi e in eterm ination of su lfi e by m ethylene b lue spectrophotom etricmetho 1M ethod s: Thioacetam i ewasues in preparing the stan ar solution series, optmi ize eterm ina2 tion con ition was obtaine 1Resu lts: The coefficient of correlation is 01 9996 at the range of 0~ 01 20 mg/L, the precision is 21 42% ~ 6157% an the recovery is 931 5% ~ 103% 1 Conclu sion: Thism etho is fast, accurate an reliab le1 It overcom es the isa van tage of the original GB m etho in wh ich the so ium su lfi e stan ar solution is unstab le an har to prepare1 [ K ey words] Th ioacetami e; Stan ar solution; Methylene b lue; Su lfi e , , , , ( - S- S 112 试剂 - ), , , 11211 [ Q( S2- ) = 100 L g/ml] : , , 01 2344 g 1000 ml 7, 4 , 11212 [Q( S2- ) = 101 0 L g/ml]: Na S# nH O ( n = 7~ 9) , 2 2